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学科主题: 物理化学
题名: A Review on the Synthesis and Applications of Mesostructured Transition Metal Phosphates
作者: Lin, Ronghe1;  Ding, Yunjie1, 2
通讯作者: 丁云杰
关键词: transition metal phosphate ;  mesostructure ;  synthesis method ;  application
刊名: MATERIALS
发表日期: 2013
DOI: 10.3390/ma6010217
卷: 6, 期:1, 页:217-243
收录类别: SCI
合作性质: 
文章类型: Review
部门归属: DNL08
项目归属: DNL0805
产权排名: 待补充
WOS标题词: Science & Technology ;  Technology
类目[WOS]: Materials Science, Multidisciplinary
资助者: 1,1
研究领域[WOS]: Materials Science
英文摘要: Considerable efforts have been devoted to extending the range of the elemental composition of mesoporous materials since the pioneering work of the M41S family of ordered mesoporous silica by Mobil researchers. The synthesis of transition metal-containing mesostructured materials with large surface area and high porosity has drawn great attention for its potential applications in acid and redox catalysis, photocatalysis, proton conducting devices, environmental restoration and so on. Thus, various transition metals-containing mesoporous materials, including transition metal-substituted mesoporous silicates, mesostructured transition metal oxides and transition metal phosphates (TMP), have been documented in the literature. Among these, mesostructured TMP materials are less studied, but possess some unique features, partly because of the easy and facile functionalization of PO4 and/or P-OH groups, rendering them interesting functional materials. This review first introduced the general synthesis strategies for manufacturing mesostructured TMP materials, as well as advantages and disadvantages of the respective method; then, we surveyed the ongoing developments of fabrication and application of the TMP materials in three groups on the basis of their components and application fields. Future perspectives on existing problems related to the present synthesis routes and further modifying of the functional groups for the purpose of tailoring special physical-chemical properties to meet wide application requirements were also provided in the last part.
关键词[WOS]: MESOPOROUS MOLECULAR-SIEVES ;  HIGH-SURFACE-AREA ;  POROUS ZIRCONIUM-PHOSPHATE ;  VANADIUM PHOSPHORUS OXIDES ;  NEUTRAL TEMPLATING ROUTE ;  TITANIUM OXO-PHOSPHATE ;  SINGLE-CRYSTAL CR2O3 ;  IRON PHOSPHATE ;  ASSISTED SYNTHESIS ;  THERMAL-STABILITY
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000314037600014
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/119085
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China

Recommended Citation:
Lin, Ronghe,Ding, Yunjie. A Review on the Synthesis and Applications of Mesostructured Transition Metal Phosphates[J]. MATERIALS,2013,6(1):217-243.
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