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学科主题: 物理化学
题名: New and Efficient Synthesis of 1,3-Dienylphosphonates by Palladium-Catalyzed Substitution of Propargylic Esters to Diethyl Phosphite
作者: Liu, Xiao-Ning1;  Guo, Wei-Lei1, 2;  Hou, Chuan-Jin1;  Hu, Xiang-Ping2
通讯作者: 侯传金 ;  胡向平
关键词: 1 ;  3-Dienylphosphonates ;  diethyl phosphite ;  Pd-catalyzed ;  propargylic substitution
刊名: SYNTHETIC COMMUNICATIONS
发表日期: 2013-10-02
DOI: 10.1080/00397911.2012.725795
卷: 43, 期:19, 页:2622-2626
收录类别: SCI ;  CCR
合作性质: 
文章类型: Article
部门归属: 2
项目归属: 02T2
产权排名: 待补充
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
资助者: 2,2
研究领域[WOS]: Chemistry
英文摘要: An efficient route to the synthesis of 1,3-dienylphosphonates (1) has been developed for the first time by the substitution of propargylic esters (2) to the diethyl phosphite (3) nucleophile in the presence of Pd-2(dba)(3)center dot CHCl3 (2mol %) and 2,2-bis(diphenylphosphino)-1,1-binaphthyl (4mol%). Both the alkyl and aryl 1,3-dienylphosphonates can be prepared from this transformation. Supplemental materials are available for this article. Go to the publisher's online edition of Synthetic Communications (R) to view the free supplemental file.
关键词[WOS]: STEREOSELECTIVE-SYNTHESIS ;  1-ALKYNYLPHOSPHONATES ;  ISOMERIZATION ;  CYCLOADDITION ;  PHOSPHONATE ;  DERIVATIVES ;  OXIDE
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000320914200008
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/119095
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Dalian Polytech Univ, Sch Light Ind & Chem Engn, Dalian 116034, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

Recommended Citation:
Liu, Xiao-Ning,Guo, Wei-Lei,Hou, Chuan-Jin,et al. New and Efficient Synthesis of 1,3-Dienylphosphonates by Palladium-Catalyzed Substitution of Propargylic Esters to Diethyl Phosphite[J]. SYNTHETIC COMMUNICATIONS,2013,43(19):2622-2626.
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