DICP OpenIR
Subject Area物理化学
New and Efficient Synthesis of 1,3-Dienylphosphonates by Palladium-Catalyzed Substitution of Propargylic Esters to Diethyl Phosphite
Liu, Xiao-Ning1; Guo, Wei-Lei1,2; Hou, Chuan-Jin1; Hu, Xiang-Ping2; Hou CJ(侯传金); Hu XP(胡向平)
Keyword1 3-dienylphosphonates Diethyl Phosphite Pd-catalyzed Propargylic Substitution
Source PublicationSYNTHETIC COMMUNICATIONS
2013-10-02
ISSN0039-7911
DOI10.1080/00397911.2012.725795
Volume43Issue:19Pages:2622-2626
Indexed BySCI ; CCR
Cooperation Status
SubtypeArticle
Department2
Funding Project02T2
Contribution Rank待补充
WOS HeadingsScience & Technology ; Physical Sciences
Funding Organization2,2 ; 2,2 ; 2,2 ; 2,2
WOS SubjectChemistry, Organic
WOS Research AreaChemistry
WOS KeywordSTEREOSELECTIVE-SYNTHESIS ; 1-ALKYNYLPHOSPHONATES ; ISOMERIZATION ; CYCLOADDITION ; PHOSPHONATE ; DERIVATIVES ; OXIDE
AbstractAn efficient route to the synthesis of 1,3-dienylphosphonates (1) has been developed for the first time by the substitution of propargylic esters (2) to the diethyl phosphite (3) nucleophile in the presence of Pd-2(dba)(3)center dot CHCl3 (2mol %) and 2,2-bis(diphenylphosphino)-1,1-binaphthyl (4mol%). Both the alkyl and aryl 1,3-dienylphosphonates can be prepared from this transformation. Supplemental materials are available for this article. Go to the publisher's online edition of Synthetic Communications (R) to view the free supplemental file.
Language英语
Funding Organization2,2 ; 2,2 ; 2,2 ; 2,2
URL查看原文
WOS IDWOS:000320914200008
Citation statistics
Cited Times:3[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/119095
Collection中国科学院大连化学物理研究所
Corresponding AuthorHou CJ(侯传金); Hu XP(胡向平)
Affiliation1.Dalian Polytech Univ, Sch Light Ind & Chem Engn, Dalian 116034, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Liu, Xiao-Ning,Guo, Wei-Lei,Hou, Chuan-Jin,et al. New and Efficient Synthesis of 1,3-Dienylphosphonates by Palladium-Catalyzed Substitution of Propargylic Esters to Diethyl Phosphite[J]. SYNTHETIC COMMUNICATIONS,2013,43(19):2622-2626.
APA Liu, Xiao-Ning,Guo, Wei-Lei,Hou, Chuan-Jin,Hu, Xiang-Ping,侯传金,&胡向平.(2013).New and Efficient Synthesis of 1,3-Dienylphosphonates by Palladium-Catalyzed Substitution of Propargylic Esters to Diethyl Phosphite.SYNTHETIC COMMUNICATIONS,43(19),2622-2626.
MLA Liu, Xiao-Ning,et al."New and Efficient Synthesis of 1,3-Dienylphosphonates by Palladium-Catalyzed Substitution of Propargylic Esters to Diethyl Phosphite".SYNTHETIC COMMUNICATIONS 43.19(2013):2622-2626.
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