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学科主题: 物理化学
题名: Heat capacities and thermodynamic properties of a 3D Cu(II) supramolecular complex
作者: Jiao, Cheng-Li1, 2;  Wang, Shuang1, 2;  Si, Xiao-Liang1, 2;  Li, Zhi-Bao1, 2;  Liu, Shuang1, 2;  Zhang, Jian1;  Sun, Li-Xian1;  Xu, Fen3;  Sun, Yu-Jia4;  Zhou, Huai-Ying5;  Sawada, Yutaka6
通讯作者: 孙立贤
关键词: Copper ;  Molar heat capacity ;  Supramolecule ;  TG ;  TMDSC
刊名: JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
发表日期: 2013-06-01
DOI: 10.1007/s10973-012-2718-3
卷: 112, 期:3, 页:1565-1571
收录类别: SCI
合作性质: 
文章类型: Article
部门归属: DNL19
项目归属: DNL1903
产权排名: 待补充
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Analytical ;  Chemistry, Physical
资助者: 1,1
研究领域[WOS]: Chemistry
英文摘要: A 3D supramolecule (H3O)(2)[Cu(2,6-pdc)(2)]center dot H2O (pdc = pyridinedicarboxylate) has been solvothermally synthesized and characterized by X-ray powder diffraction and FT-IR spectrum. The thermal decomposition characteristics of the complex were investigated by thermogravimetric analysis, which revealed a three-step mass loss process. The low-temperature molar heat capacities of crystalline (H3O)(2)[Cu(2,6-pdc)(2)]center dot H2O were measured by temperature-modulated differential scanning calorimetry for the first time. A phenomenon of glass transition was observed. The thermodynamic parameters such as entropy and enthalpy relative to 298.15 K were calculated based on the above molar heat capacity data.
关键词[WOS]: MAGNETIC-PROPERTIES ;  CRYSTAL-STRUCTURES ;  ACID ;  CALORIMETRY ;  FRAMEWORKS
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000319358500051
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/119136
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Mat & Thermochem Lab, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
3.Liaoning Normal Univ, Fac Chem & Chem Engn, Dalian 116029, Peoples R China
4.Wuhan Univ, Coll Chem & Mol Sci, Wuhan 430072, Peoples R China
5.Guilin Univ Elect Technol, Dept Mat Sci & Engn, Guilin 541004, Peoples R China
6.Tokyo Polytech Univ, Ctr Hyper Media Res, Grad Sch Engn, Atsugi, Kanagawa 2430297, Japan

Recommended Citation:
Jiao, Cheng-Li,Wang, Shuang,Si, Xiao-Liang,et al. Heat capacities and thermodynamic properties of a 3D Cu(II) supramolecular complex[J]. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY,2013,112(3):1565-1571.
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