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学科主题: 物理化学
题名: Enhanced Thermostability, Thermo-Optics, and Thermomechanical Properties of Barium Gallo-Germanium Oxyfluoride Glasses and Glass-Ceramics
作者: Zhang, Shaoqian1;  Xu, Mingxiu1;  Chen, Xi1;  Zhang, Yuelong1;  Calvez, Laurant2;  Zhang, Xianghua2;  Xu, Yinsheng3;  Huai, Ying1;  Jin, Yuqi1
通讯作者: 张绍骞
刊名: JOURNAL OF THE AMERICAN CERAMIC SOCIETY
发表日期: 2013-08-01
DOI: 10.1111/jace.12477
卷: 96, 期:8, 页:2461-2466
收录类别: SCI
合作性质: 
文章类型: Article
部门归属: 7
项目归属: 07T1
产权排名: 待补充
WOS标题词: Science & Technology ;  Technology
类目[WOS]: Materials Science, Ceramics
资助者: 1,1
研究领域[WOS]: Materials Science
英文摘要: Serial substitutions of BaF2 for BaO in BaO-Ga2O3-GeO2 glasses were performed, and the effects of the substitutions on the glass properties were investigated. The glass transition temperature, density, refractive index, thermo-optics coefficient, and figure of merit for thermal shock decreased with the replacement of oxygen by fluorine. On the other hand, the glass-forming ability increased. Fluorine substitution removed the absorption band of hydroxyl near 2.9m. Raman scattering spectroscopy was used to characterize the fluorogermanate glasses. The crystallization process of the glass-ceramics under different heat-treatment conditions was also investigated using differential scanning calorimetry, X-ray diffraction, scanning electron microscopy, and atomic force microscopy. The thermal and mechanical properties were improved by controlling the crystal size of the near- and middle-infrared transparent glass-ceramics.
关键词[WOS]: X-RAY-ABSORPTION ;  BAO-GA2O3-GEO2 GLASSES ;  RAMAN ;  SPECTRA ;  WINDOWS ;  FIBER
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000322965300018
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/119141
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Key Lab Chem Lasers, Dalian 116023, Peoples R China
2.Univ Rennes 1, UMR6226, Lab Verres & Ceram, Chim Sect, F-35042 Rennes, France
3.Ningbo Univ, Fac Mat Sci & Chem Engn, Ningbo 315211, Zhejiang, Peoples R China

Recommended Citation:
Zhang, Shaoqian,Xu, Mingxiu,Chen, Xi,et al. Enhanced Thermostability, Thermo-Optics, and Thermomechanical Properties of Barium Gallo-Germanium Oxyfluoride Glasses and Glass-Ceramics[J]. JOURNAL OF THE AMERICAN CERAMIC SOCIETY,2013,96(8):2461-2466.
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