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学科主题: 物理化学
题名: Syntheses, structures and chemical sensing properties of three complexes with mixed ligands of carboxylate and bipyridine
作者: Jiao, Chengli1, 2;  Li, Fen1;  Zhang, Jian1;  Li, Zhangpeng3;  Wang, Shuang1, 2;  Wang, Zhonggang4;  Yu, Hao4;  Li, Zhibao1, 2;  Liu, Shuang1, 2;  Wang, Ziqiang1, 2;  Jiang, Xia1, 2;  Sun, Lixian1, 5;  Xu, Fen5, 6
通讯作者: 孙立贤
刊名: DALTON TRANSACTIONS
发表日期: 2013
DOI: 10.1039/c2dt31867a
卷: 42, 期:5, 页:1346-1351
收录类别: SCI
合作性质: 
文章类型: Article
部门归属: DNL19
项目归属: DNL1903
产权排名: 待补充
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Inorganic & Nuclear
资助者: 1,1
研究领域[WOS]: Chemistry
英文摘要: Three mixed-ligand coordination polymers, [Cu(oda)(2,2'-bipy)](2) (1), Ni-2(oda)(2)(4,4'-bipy)center dot DMF (2), and [{Ni(oda)(H2O)(2)}(2)(mu-4,4'-bipy)]center dot 2H(2)O (3) were synthesized and characterized. Complex 1 features a 1D chain via intermolecular pi-pi interactions. Complex 2 is a novel 3D microporous coordination polymer with 1D polarized channels. Complex 3 forms a 3D network via extensive hydrogen bonding interactions. Thermogravimetric analyses have been studied. The chemical sensing properties have been investigated in situ by quartz crystal microbalance (QCM). Complex 1 has a good sensitivity to toluene, complexes 2 and 3 have exceptionally high selectivity and sensitivity to water over organic solvents.
关键词[WOS]: METAL-ORGANIC FRAMEWORKS ;  ADSORPTION PROPERTIES ;  COORDINATION POLYMER ;  CRYSTAL-STRUCTURE ;  OXYDIACETIC ACID ;  X-RAY ;  COMPOUND ;  THIODIACETATE ;  SEPARATION ;  BEHAVIOR
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000313616600006
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/119172
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Mat & Thermochem Lab, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
3.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China
4.Dalian Univ Technol, Dept Polymer Sci & Engn, State Key Lab Fine Chem, Sch Chem Engn, Dalian 116012, Peoples R China
5.Guilin Univ Elect Technol, Fac Mat Sci & Engn, Guilin 541004, Peoples R China
6.Liaoning Normal Univ, Fac Chem & Chem Engn, Dalian 116029, Peoples R China

Recommended Citation:
Jiao, Chengli,Li, Fen,Zhang, Jian,et al. Syntheses, structures and chemical sensing properties of three complexes with mixed ligands of carboxylate and bipyridine[J]. DALTON TRANSACTIONS,2013,42(5):1346-1351.
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