DICP OpenIR
Subject Area物理化学
Hybrid Artificial Photosynthetic Systems Comprising Semiconductors as Light Harvesters and Biomimetic Complexes as Molecular Cocatalysts
Wen, Fuyu; Li, Can1,2; Li C(李灿)
Source PublicationACCOUNTS OF CHEMICAL RESEARCH
2013-11-19
DOI10.1021/ar300224u
Volume46Issue:11Pages:2355-2364
Indexed BySCI
Cooperation Status
SubtypeReview
Department5
Funding Project503
Contribution Rank待补充
WOS HeadingsScience & Technology ; Physical Sciences
Funding Organization1,1 ; 1,1 ; 1,1 ; 1,1
WOS SubjectChemistry, Multidisciplinary
WOS Research AreaChemistry
WOS KeywordHYDROGENASE ACTIVE-SITE ; PHOTOCATALYTIC H-2 EVOLUTION ; HIGH QUANTUM EFFICIENCY ; VISIBLE-LIGHT ; IRON HYDROGENASE ; CARBON-DIOXIDE ; WATER-OXIDATION ; CO2 REDUCTION ; ELECTROCATALYTIC REDUCTION ; CHARGE SEPARATION
AbstractSolar fuel production through artificial photosynthesis may be a key to generating abundant and clean energy, thus addressing the high energy needs of the world's expanding population. As the crucial components of photosynthesis, the artificial photosynthetic system should be composed of a light harvester (e.g., semiconductor or molecular dye), a reduction cocatalyst (e.g., hydrogenase mimic, noble metal), and an oxidation cocatalyst (e.g., photosystem II mimic for oxygen evolution from water oxidation). Solar fuel production catalyzed by an artificial photosynthetic system starts from the absorption of sunlight by the light harvester, where charge separation takes place, followed by a charge transfer to the reduction and oxidation cocatalysts, where redox reaction processes occur. One of the most challenging problems is to develop an artificial photosynthetic solar fuel production system that is both highly efficient and stable. The assembly of cocatalysts on the semiconductor (light harvester) not only can facilitate the charge separation, but also can lower the activation energy or overpotential for the reactions. An efficient light harvester loaded with suitable reduction and oxidation cocatalysts is the key for high efficiency of artificial photosynthetic systems.
Language英语
Funding Organization1,1 ; 1,1 ; 1,1 ; 1,1
URL查看原文
WOS IDWOS:000327360800002
Citation statistics
Cited Times:183[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/119179
Collection中国科学院大连化学物理研究所
Corresponding AuthorLi C(李灿)
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Wen, Fuyu,Li, Can,Li C. Hybrid Artificial Photosynthetic Systems Comprising Semiconductors as Light Harvesters and Biomimetic Complexes as Molecular Cocatalysts[J]. ACCOUNTS OF CHEMICAL RESEARCH,2013,46(11):2355-2364.
APA Wen, Fuyu,Li, Can,&李灿.(2013).Hybrid Artificial Photosynthetic Systems Comprising Semiconductors as Light Harvesters and Biomimetic Complexes as Molecular Cocatalysts.ACCOUNTS OF CHEMICAL RESEARCH,46(11),2355-2364.
MLA Wen, Fuyu,et al."Hybrid Artificial Photosynthetic Systems Comprising Semiconductors as Light Harvesters and Biomimetic Complexes as Molecular Cocatalysts".ACCOUNTS OF CHEMICAL RESEARCH 46.11(2013):2355-2364.
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