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学科主题: 物理化学
题名: Synthesis of Tetrasubstituted Pyrroles from Terminal Alkynes and Imines
作者: Hu, Yancheng1;  Wang, Chunxiang1;  Wang, Dongping1;  Wu, Fan1;  Wan, Boshun1
通讯作者: 万伯顺
刊名: ORGANIC LETTERS
发表日期: 2013-06-21
DOI: 10.1021/ol401369d
卷: 15, 期:12, 页:3146-3149
收录类别: SCI ;  IC ;  CCR
合作性质: 
文章类型: Article
部门归属: 2
项目归属: 202
产权排名: 待补充
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
资助者: 1,1
研究领域[WOS]: Chemistry
英文摘要: Tetrasubstituted pyrroles can be obtained via the reaction of terminal alkynes and Imines using (BuLi)-Bu-n as the base In one step with high chemoselectivity (method 1). Alternatively, the intermediate propargylamines can also react with imines to afford tetrasubstituted pyrroles when using LiHMDS as the base (method 2), which provides a complementary method to construct the pyrroles with different substituents.
关键词[WOS]: H BOND FUNCTIONALIZATION ;  SOLVENT-FREE CONDITIONS ;  POLYSUBSTITUTED PYRROLES ;  3-COMPONENT SYNTHESIS ;  ONE-POT ;  AEROBIC SYNTHESIS ;  ANNULATION ;  AMINES ;  FURANS ;  WATER
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000320979000065
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/119195
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

Recommended Citation:
Hu, Yancheng,Wang, Chunxiang,Wang, Dongping,et al. Synthesis of Tetrasubstituted Pyrroles from Terminal Alkynes and Imines[J]. ORGANIC LETTERS,2013,15(12):3146-3149.
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