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学科主题物理化学
Schiff base polymers derived from 2,5-diformylfuran
Xiang, Tengfei1; Liu, Xiumin1; Yi, Ping2; Guo, Mingming3; Chen, Yusheng1; Wesdemiotis, Chrys1; Xu, Jie4; Pang, Yi1; Yi Pang
关键词Schiff Base Condensation Polymerization Mass Spectroscopy Nmr
刊名POLYMER INTERNATIONAL
2013-10-01
DOI10.1002/pi.4452
62期:10页:1517-1523
收录类别SCI
合作性质
文章类型Article
部门归属DNL06
项目归属DNL0601
产权排名待补充
WOS标题词Science & Technology ; Physical Sciences
资助者4,7 ; 4,7 ; 4,7 ; 4,7
类目[WOS]Polymer Science
研究领域[WOS]Polymer Science
关键词[WOS]POLYAZOMETHINES ; OXIDATION ; COMPLEXES
英文摘要Polymerization of 2,5-diformylfuran with two primary amines was carried out in acetonitrile and ethanol at room temperature. The reaction was characterized using a combination of mass spectroscopy and NMR spectroscopy, which revealed the clean formation of the imine -CH N-functional group. Although some cyclic products were detected from mass spectroscopy, the ring size was limited to products that have the -CH N-group only in anti-geometry. The furan Schiff bases exhibit good thermal stability. While mass spectra evidenced oligomers of different lengths, cross-polarization magic angle spinning 13C NMR spectra of the insoluble polymer revealed the linear structure as proposed. (C) 2013 Society of Chemical Industry
语种英语
资助者4,7 ; 4,7 ; 4,7 ; 4,7
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WOS记录号WOS:000323887700015
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被引频次:23[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/119238
专题中国科学院大连化学物理研究所
通讯作者Yi Pang
作者单位1.Univ Akron, Dept Chem, Akron, OH 44325 USA
2.Univ Akron, Dept Civil Engn, Akron, OH 44325 USA
3.Univ Akron, Dept Polymer Sci, Akron, OH 44325 USA
4.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian 116023, Peoples R China
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Xiang, Tengfei,Liu, Xiumin,Yi, Ping,et al. Schiff base polymers derived from 2,5-diformylfuran[J]. POLYMER INTERNATIONAL,2013,62(10):1517-1523.
APA Xiang, Tengfei.,Liu, Xiumin.,Yi, Ping.,Guo, Mingming.,Chen, Yusheng.,...&Yi Pang.(2013).Schiff base polymers derived from 2,5-diformylfuran.POLYMER INTERNATIONAL,62(10),1517-1523.
MLA Xiang, Tengfei,et al."Schiff base polymers derived from 2,5-diformylfuran".POLYMER INTERNATIONAL 62.10(2013):1517-1523.
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