DICP OpenIR
Subject Area物理化学
Schiff base polymers derived from 2,5-diformylfuran
Xiang, Tengfei1; Liu, Xiumin1; Yi, Ping2; Guo, Mingming3; Chen, Yusheng1; Wesdemiotis, Chrys1; Xu, Jie4; Pang, Yi1; Yi Pang
KeywordSchiff Base Condensation Polymerization Mass Spectroscopy Nmr
Source PublicationPOLYMER INTERNATIONAL
2013-10-01
DOI10.1002/pi.4452
Volume62Issue:10Pages:1517-1523
Indexed BySCI
Cooperation Status
SubtypeArticle
DepartmentDNL06
Funding ProjectDNL0601
Contribution Rank待补充
WOS HeadingsScience & Technology ; Physical Sciences
Funding Organization4,7 ; 4,7 ; 4,7 ; 4,7
WOS SubjectPolymer Science
WOS Research AreaPolymer Science
WOS KeywordPOLYAZOMETHINES ; OXIDATION ; COMPLEXES
AbstractPolymerization of 2,5-diformylfuran with two primary amines was carried out in acetonitrile and ethanol at room temperature. The reaction was characterized using a combination of mass spectroscopy and NMR spectroscopy, which revealed the clean formation of the imine -CH N-functional group. Although some cyclic products were detected from mass spectroscopy, the ring size was limited to products that have the -CH N-group only in anti-geometry. The furan Schiff bases exhibit good thermal stability. While mass spectra evidenced oligomers of different lengths, cross-polarization magic angle spinning 13C NMR spectra of the insoluble polymer revealed the linear structure as proposed. (C) 2013 Society of Chemical Industry
Language英语
Funding Organization4,7 ; 4,7 ; 4,7 ; 4,7
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WOS IDWOS:000323887700015
Citation statistics
Cited Times:30[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/119238
Collection中国科学院大连化学物理研究所
Corresponding AuthorYi Pang
Affiliation1.Univ Akron, Dept Chem, Akron, OH 44325 USA
2.Univ Akron, Dept Civil Engn, Akron, OH 44325 USA
3.Univ Akron, Dept Polymer Sci, Akron, OH 44325 USA
4.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Xiang, Tengfei,Liu, Xiumin,Yi, Ping,et al. Schiff base polymers derived from 2,5-diformylfuran[J]. POLYMER INTERNATIONAL,2013,62(10):1517-1523.
APA Xiang, Tengfei.,Liu, Xiumin.,Yi, Ping.,Guo, Mingming.,Chen, Yusheng.,...&Yi Pang.(2013).Schiff base polymers derived from 2,5-diformylfuran.POLYMER INTERNATIONAL,62(10),1517-1523.
MLA Xiang, Tengfei,et al."Schiff base polymers derived from 2,5-diformylfuran".POLYMER INTERNATIONAL 62.10(2013):1517-1523.
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