White Light Assisted Photosensitized Synthesis of Ag Nanoparticles: Excited-State Hydrogen Bonding Roles

doi:10.1021/jp4030624

DICP OpenIR

学科主题	物理化学
	White Light Assisted Photosensitized Synthesis of Ag Nanoparticles: Excited-State Hydrogen Bonding Roles
	Yang, Yang 1; Liu, Lei 1,3; Yin, Hongming 1,2; Xu, Dali 1; Liu, Guangye 1; Song, Xiancheng 4; Liu, Jianyong 1; Yin HM(尹鸿鸣); Liu JY(刘建勇)
刊名	JOURNAL OF PHYSICAL CHEMISTRY C
	2013-06-06
DOI	10.1021/jp4030624
卷	117 期:22 页:11858-11865
收录类别	SCI
合作性质	英
文章类型	Article
部门归属	11
项目归属	1101
产权排名	待补充
WOS标题词	Science & Technology ; Physical Sciences ; Technology
资助者	1，1 ; 1，1 ; 1，1 ; 1，1
类目[WOS]	Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
研究领域[WOS]	Chemistry ; Science & Technology - Other Topics ; Materials Science
关键词[WOS]	PHOTOCHEMICAL-SYNTHESIS ; GOLD NANOPARTICLES ; PROTON-TRANSFER ; FLUORESCENCE ; DYNAMICS ; BENZIL ; NANOSTRUCTURES ; IRRADIATION ; EXCITATION ; MECHANISM
英文摘要	Ag nanoparticles (NPs) with different surface morphologies can be synthesized through white light irradiation of photochemically prepared Ag nanoseeds within 20 min. The fundamental photophysical and photochemical properties of benzil in deaerated solvents at room temperature are investigated through analyzing nanosecond absorption spectra. In ethanol, after the single photon excitation of benzil by 355 nm nanosecond laser pulses, one kind of reactive intermediate with a long-lived lifetime of 375.83 +/- 93.70 mu s is generated and capable of reducing the coexisted Ag+ to generate Ag nanoseeds with their diameters in the range from 3 to 12 nm. Theoretical calculations indicate that the reactive intermediate is benzil-ethanol hydrogen-bonded complex biradical (ben-eth biradical). Furthermore, the excited-state hydrogen bonding dynamics and its influence on the photophysical and photochemical properties are discussed. White light irradiation under air can make these Ag nanoseeds grow in size with a speed of 10 nm/min and have unique morphologies. In particularly, the nanowhisker covered Ag NPs can be synthesized and possess a unique narrow optical absorption peak at 325 nm. This work not only provides insights into the mechanisms of photosensitized synthesis of Ag nanoseeds but also emphasizes the utilization of white light as a convenient and efficient tool to tailor morphologies of Ag NPs.
语种	英语
资助者	1，1 ; 1，1 ; 1，1 ; 1，1
原文出处	查看原文
WOS记录号	WOS:000320214800050
引用统计
文献类型	期刊论文
条目标识符	http://cas-ir.dicp.ac.cn/handle/321008/119263
专题	中国科学院大连化学物理研究所
通讯作者	Yin HM(尹鸿鸣); Liu JY(刘建勇)
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China 2.Dalian Maritime Univ, Dept Phys, Dalian 116026, Peoples R China 3.Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116024, Peoples R China 4.Beihang Univ, Sch Jet Prop, Beijing 100191, Peoples R China
推荐引用方式 GB/T 7714	Yang, Yang,Liu, Lei,Yin, Hongming,et al. White Light Assisted Photosensitized Synthesis of Ag Nanoparticles: Excited-State Hydrogen Bonding Roles[J]. JOURNAL OF PHYSICAL CHEMISTRY C,2013,117(22):11858-11865.
APA	Yang, Yang.,Liu, Lei.,Yin, Hongming.,Xu, Dali.,Liu, Guangye.,...&刘建勇.(2013).White Light Assisted Photosensitized Synthesis of Ag Nanoparticles: Excited-State Hydrogen Bonding Roles.JOURNAL OF PHYSICAL CHEMISTRY C,117(22),11858-11865.
MLA	Yang, Yang,et al."White Light Assisted Photosensitized Synthesis of Ag Nanoparticles: Excited-State Hydrogen Bonding Roles".JOURNAL OF PHYSICAL CHEMISTRY C 117.22(2013):11858-11865.

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