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学科主题: 物理化学
题名: Selective decomposition of cyclohexyl hydroperoxide by copper ion-containing quaternary ammonium salts in alkali-free medium
作者: Zheng, Xi1, 2;  Wang, Min1;  Sun, Zhiqiang1;  Liu, Junxia1, 2;  Ma, Jiping1;  Xu, Jie1
通讯作者: 徐杰
关键词: Quaternary ammonium salts ;  Copper ;  Cyclohexyl hydroperoxide ;  Decomposition ;  Alkali free
刊名: CATALYSIS COMMUNICATIONS
发表日期: 2013-10-05
DOI: 10.1016/j.catcom.2013.05.022
卷: 40, 页:55-58
收录类别: SCI
合作性质: 
文章类型: Article
部门归属: DNL06
项目归属: DNL0601
产权排名: 待补充
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Physical
资助者: 1,1
研究领域[WOS]: Chemistry
英文摘要: A novel catalytic system composed of quaternary ammonium salts and copper (II) chloride was prepared. The catalyst showed high conversion and selectivity in the decomposition of cyclohexyl hydroperoxide to cyclohexanol and cyclohexanone (K/A oil) at room temperature in alkali-free medium. 93% conversion with 96% selectivity for cyclohexanone and cyclohexanol could be obtained. (C) 2013 Elsevier B.V. All rights reserved.
关键词[WOS]: ONIUM SALTS ;  OXIDATION ;  LIQUIDS ;  COMPLEXES ;  CATALYSIS ;  SOLVENTS ;  DEPEROXIDATION ;  HYDROCARBONS ;  SILICA ;  O-2
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000323016400013
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/119309
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China

Recommended Citation:
Zheng, Xi,Wang, Min,Sun, Zhiqiang,et al. Selective decomposition of cyclohexyl hydroperoxide by copper ion-containing quaternary ammonium salts in alkali-free medium[J]. CATALYSIS COMMUNICATIONS,2013,40:55-58.
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