DICP OpenIR
Subject Area物理化学
Nanocrystalline gold supported on NaY as catalyst for the direct oxidation of primary alcohol to carboxylic acid with molecular oxygen in water
Zhou, Lipeng1; Yu, Wenjun1; Wu, Lin1; Liu, Zhen1; Chen, Haijun1; Yang, Xiaomei1; Su, Yunlai1; Xu, Jie2; Yang XM(杨晓梅)
KeywordAu/nay Oxidation Alcohol Carboxylic Acid
Source PublicationAPPLIED CATALYSIS A-GENERAL
2013-01-31
DOI10.1016/j.apcata.2012.11.003
Volume451Pages:137-143
Indexed BySCI
Cooperation Status
SubtypeArticle
DepartmentDNL06
Funding ProjectDNL0601
Contribution Rank待补充
WOS HeadingsScience & Technology ; Physical Sciences ; Life Sciences & Biomedicine
Funding Organization2,8 ; 2,8 ; 2,8 ; 2,8
WOS SubjectChemistry, Physical ; Environmental Sciences
WOS Research AreaChemistry ; Environmental Sciences & Ecology
WOS KeywordSELECTIVE OXIDATION ; AEROBIC OXIDATION ; CO OXIDATION ; NANOPARTICLE CATALYSTS ; CARBON-MONOXIDE ; NANO-GOLD ; TEMPERATURE ; ALDEHYDES ; ZEOLITES ; PH
AbstractAu/NaY was prepared by deposition-precipitation (DP) method using HAuCl4 as gold source. The samples were characterized by X-ray diffraction, N-2 adsorption, transmission electron microscopy and inductively coupled plasma atomic emission spectrometry. It was found that the adjustment of the surface acidity of NaY, the pH and concentration of HAuCl4 solution, and the temperature and time for DP affected the particle size, the loading and the morphology of Au on NaY. The catalytic performance of Au/NaY was studied in the oxidation of alcohols to the corresponding carboxylic acids with molecular oxygen as oxidant under basic conditions. About 100% conversion of benzyl alcohol with 95.2% isolated yield of benzoic acid was obtained at the reaction temperature of 80 degrees C for 8 h. The catalyst was recycled for four times without loss of catalytic activity. In addition, the catalyst worked well for the catalytic oxidation of various alcohols including aromatic and aliphatic alcohols to the corresponding carboxyl acids. (C) 2012 Elsevier B.V. All rights reserved.
Language英语
Funding Organization2,8 ; 2,8 ; 2,8 ; 2,8
URL查看原文
WOS IDWOS:000315069200019
Citation statistics
Cited Times:8[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/119342
Collection中国科学院大连化学物理研究所
Corresponding AuthorYang XM(杨晓梅)
Affiliation1.Zhengzhou Univ, Coll Chem & Mol Engn, Zhengzhou 450001, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Zhou, Lipeng,Yu, Wenjun,Wu, Lin,et al. Nanocrystalline gold supported on NaY as catalyst for the direct oxidation of primary alcohol to carboxylic acid with molecular oxygen in water[J]. APPLIED CATALYSIS A-GENERAL,2013,451:137-143.
APA Zhou, Lipeng.,Yu, Wenjun.,Wu, Lin.,Liu, Zhen.,Chen, Haijun.,...&杨晓梅.(2013).Nanocrystalline gold supported on NaY as catalyst for the direct oxidation of primary alcohol to carboxylic acid with molecular oxygen in water.APPLIED CATALYSIS A-GENERAL,451,137-143.
MLA Zhou, Lipeng,et al."Nanocrystalline gold supported on NaY as catalyst for the direct oxidation of primary alcohol to carboxylic acid with molecular oxygen in water".APPLIED CATALYSIS A-GENERAL 451(2013):137-143.
Files in This Item:
File Name/Size DocType Version Access License
2013ixpSiplDMg.PDF(1734KB) 开放获取CC BY-NC-SAApplication Full Text
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Zhou, Lipeng]'s Articles
[Yu, Wenjun]'s Articles
[Wu, Lin]'s Articles
Baidu academic
Similar articles in Baidu academic
[Zhou, Lipeng]'s Articles
[Yu, Wenjun]'s Articles
[Wu, Lin]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Zhou, Lipeng]'s Articles
[Yu, Wenjun]'s Articles
[Wu, Lin]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.