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学科主题物理化学
Graphene oxide and lithium amidoborane: a new way to bridge chemical and physical approaches for hydrogen storage
Li, Fen1,2; Gao, Junfeng2; Zhang, Jian1; Xu, Fen3,4; Zhao, Jijun2; Sun, Lixian1,3; Sun LX(孙立贤)
刊名JOURNAL OF MATERIALS CHEMISTRY A
2013
DOI10.1039/c3ta10800g
1期:27页:8016-8022
收录类别SCI
合作性质
文章类型Article
部门归属DNL19
项目归属DNL1903
产权排名待补充
WOS标题词Science & Technology ; Physical Sciences ; Technology
资助者1,1 ; 1,1 ; 1,1 ; 1,1
类目[WOS]Chemistry, Physical ; Energy & Fuels ; Materials Science, Multidisciplinary
研究领域[WOS]Chemistry ; Energy & Fuels ; Materials Science
关键词[WOS]AMMONIA-BORANE DEHYDROGENATION ; METAL AMIDOBORANES ; AB-INITIO ; BASIS-SET ; NANOTUBES ; ALKALI ; ADDUCTS ; RELEASE ; ENERGY ; REGENERATION
英文摘要The incorporation of lithium amidoborane (LiAB) into graphene oxide (GO) and the dehydrogenation process of the GO-LiAB complex have been investigated for combining the chemical and physical hydrogen storage approaches. The obtained adsorption energy and minimum energy pathway (MEP) demonstrate that both of the two dominant groups of -O- and OH- contribute to the facile combination of GO and LiAB (GO(3)-LiAB). The GO(3)-LiAB complex has a better dehydrogenation performance than the pristine LiAB, which also indicates the feasibility of doping Li atoms on the GO surface. Atomic charge and bond length analyses match well with the MEP prediction. By dehydrogenation of the GO(3)-LiAB complex, we also achieve uniform metal doping on the GO surface for physisorption of H-2. The GO-Li-(n) products can store up to 5 wt% H-2 and the GO-(Li3N3B3)((n)) can still store 5 wt% H-2. The dehydrogenation product of the GO(3)-LiAB complex has bridged the chemical and physical hydrogen storage approaches to move towards on-board hydrogen storage applications, which expands the scope for designing more efficient hydrogen storage materials.
语种英语
资助者1,1 ; 1,1 ; 1,1 ; 1,1
原文出处查看原文
WOS记录号WOS:000320551200024
引用统计
被引频次:17[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/119372
专题中国科学院大连化学物理研究所
通讯作者Sun LX(孙立贤)
作者单位1.Dalian Inst Chem Phys, Mat & Thermochem Lab, Dalian 116023, Peoples R China
2.Dalian Univ Technol, Key Lab Mat Modificat Laser Ion & Electron Beams, Minist Educ, Dalian 116024, Peoples R China
3.Guilin Univ Elect Technol, Fac Mat Sci & Engn, Guilin 541004, Peoples R China
4.Liaoning Normal Univ, Fac Chem & Chem Engn, Dalian 116029, Peoples R China
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GB/T 7714
Li, Fen,Gao, Junfeng,Zhang, Jian,et al. Graphene oxide and lithium amidoborane: a new way to bridge chemical and physical approaches for hydrogen storage[J]. JOURNAL OF MATERIALS CHEMISTRY A,2013,1(27):8016-8022.
APA Li, Fen.,Gao, Junfeng.,Zhang, Jian.,Xu, Fen.,Zhao, Jijun.,...&孙立贤.(2013).Graphene oxide and lithium amidoborane: a new way to bridge chemical and physical approaches for hydrogen storage.JOURNAL OF MATERIALS CHEMISTRY A,1(27),8016-8022.
MLA Li, Fen,et al."Graphene oxide and lithium amidoborane: a new way to bridge chemical and physical approaches for hydrogen storage".JOURNAL OF MATERIALS CHEMISTRY A 1.27(2013):8016-8022.
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