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学科主题: 物理化学
题名: Ru(II) pyridyl-based NNN complex catalysts for (asymmetric) transfer hydrogenation of ketones at room temperature
作者: Du Wangming1;  Wang Qingfu1;  Yu Zhengkun1
通讯作者: 余正坤
关键词: Ru(II) complex ;  Asymmetric transfer hydrogenation ;  Chiral imidazolinyl ;  Benzimidazolyl ;  Ketone
刊名: CHINESE JOURNAL OF CATALYSIS
发表日期: 2013-07-01
DOI: 10.1016/S1872-2067(12)60583-X
卷: 34, 期:7, 页:1373-1377
收录类别: SCI
合作性质: 
文章类型: Article
部门归属: 2
项目归属: 203
产权排名: 待补充
WOS标题词: Science & Technology ;  Physical Sciences ;  Technology
类目[WOS]: Chemistry, Applied ;  Chemistry, Physical ;  Engineering, Chemical
资助者: 1,1
研究领域[WOS]: Chemistry ;  Engineering
英文摘要: Ru(II) complexes bearing pyridyl-based benzimidazolyl-imidazolinyl tridentate NNN ligands were synthesized and structurally characterized. Their molecular structure was confirmed by X-ray crystallography. These complexes demonstrated good to excellent catalytic activity in the asymmetric transfer hydrogenation of ketones at room temperature, achieving up to 99% yields and 97% ee values. (C) 2013, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier RV All rights reserved.
关键词[WOS]: PYRAZOLYL-IMIDAZOLYL LIGAND ;  RUTHENIUM(II) COMPLEXES ;  ENANTIOSELECTIVE HYDROGENATION ;  H-2 HYDROGENATION ;  PINCER COMPLEXES ;  BEARING ;  NANOPARTICLES
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000322425500012
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/119402
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China

Recommended Citation:
Du Wangming,Wang Qingfu,Yu Zhengkun. Ru(II) pyridyl-based NNN complex catalysts for (asymmetric) transfer hydrogenation of ketones at room temperature[J]. CHINESE JOURNAL OF CATALYSIS,2013,34(7):1373-1377.
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