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学科主题物理化学
Iron-Catalyzed Cycloaddition Reaction of Diynes and Cyanamides at Room Temperature
Wang, Chunxiang; Wang, Dongping; Xu, Fen; Pan, Bin; Wan, Boshun; Wan BS(万伯顺)
刊名JOURNAL OF ORGANIC CHEMISTRY
2013-04-05
DOI10.1021/jo400057t
78期:7页:3065-3072
收录类别SCI ; IC ; CCR
合作性质
文章类型Article
部门归属2
项目归属202
产权排名待补充
WOS标题词Science & Technology ; Physical Sciences
资助者1,1 ; 1,1 ; 1,1 ; 1,1
类目[WOS]Chemistry, Organic
研究领域[WOS]Chemistry
关键词[WOS]MEDIATED 2+2+2 CYCLOTRIMERIZATION ; INTRAMOLECULAR CYCLOTRIMERIZATION ; REGIOSELECTIVE CYCLOTRIMERIZATION ; SUBSTITUTED PYRIDINES ; UNACTIVATED NITRILES ; COUPLING REACTIONS ; CARBON-HETEROATOM ; ORGANIC-SYNTHESIS ; OLEFIN COMPLEXES ; MILD CONDITIONS
英文摘要An iron-catalyzed [2 + 2 + 2] cycloaddition reaction of diynes and cyanamides at room temperature is reported. Highly substituted 2-aminopyridines were obtained in good to excellent yields with high regioselectivity. Insights toward the reaction process were investigated through in situ IR spectra and control experiments. In this iron-catalyzed cycloaddition reaction, the active iron species was generated only in the presence of both alkynes and nitriles. The lower reaction temperature, broad substrates scope, and inversed regioselectivity make it a complementary method to the previously developed iron catalytic system.
语种英语
资助者1,1 ; 1,1 ; 1,1 ; 1,1
原文出处查看原文
WOS记录号WOS:000317327800025
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/119418
专题中国科学院大连化学物理研究所
通讯作者Wan BS(万伯顺)
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
推荐引用方式
GB/T 7714
Wang, Chunxiang,Wang, Dongping,Xu, Fen,et al. Iron-Catalyzed Cycloaddition Reaction of Diynes and Cyanamides at Room Temperature[J]. JOURNAL OF ORGANIC CHEMISTRY,2013,78(7):3065-3072.
APA Wang, Chunxiang,Wang, Dongping,Xu, Fen,Pan, Bin,Wan, Boshun,&万伯顺.(2013).Iron-Catalyzed Cycloaddition Reaction of Diynes and Cyanamides at Room Temperature.JOURNAL OF ORGANIC CHEMISTRY,78(7),3065-3072.
MLA Wang, Chunxiang,et al."Iron-Catalyzed Cycloaddition Reaction of Diynes and Cyanamides at Room Temperature".JOURNAL OF ORGANIC CHEMISTRY 78.7(2013):3065-3072.
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