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学科主题物理化学
Synthesis of renewable diesel with the 2-methylfuran, butanal and acetone derived from lignocellulose
Li, Guangyi1,2; Li, Ning1; Yang, Jinfan1,2; Wang, Aiqin1; Wang, Xiaodong1; Cong, Yu1; Zhang, Tao1; Zhang T(张涛)
关键词Lignocellulose Diesel Hydroxyalkylation/alkylation Hydrodeoxygenation Ni-wxc/c
刊名BIORESOURCE TECHNOLOGY
2013-04-01
ISSN0960-8524
DOI10.1016/j.biortech.2013.01.116
134页:66-72
收录类别SCI
合作性质
文章类型Article
部门归属15
项目归属1501
产权排名待补充
WOS标题词Science & Technology ; Life Sciences & Biomedicine ; Technology
资助者1,1 ; 1,1 ; 1,1 ; 1,1
类目[WOS]Agricultural Engineering ; Biotechnology & Applied Microbiology ; Energy & Fuels
研究领域[WOS]Agriculture ; Biotechnology & Applied Microbiology ; Energy & Fuels
关键词[WOS]HIGH-QUALITY DIESEL ; HIGH-SURFACE-AREA ; MESOPOROUS CARBON ; SOLID ACID ; CATALYTIC CONVERSION ; CARBIDE CATALYSTS ; ETHYLENE-GLYCOL ; CELLULOSE ; BIOMASS ; HEMICELLULOSE
英文摘要In this work, the hydroxyalkylation/alkylation of 2-methylfuran (2-MF) with acetone and butanal was investigated over a series of solid acid catalysts. Among the investigated candidates, Nafion-212 resin demonstrated the highest activity and stability for both reactions. Butanal is more reactive than acetone in hydroxyalkylation/alkylation, which can be rationalized by the steric and electronic effects of alkyl group. Finally, the hydroxyalkylation/alkylation products as prepared were directly hydrodeoxygenated over Pd/C, Pt/C and Ni-WxC/C catalysts. Evidently higher carbon yields to diesel were obtained when hydroxyalkylation/alkylation product of 2-MF with butanal was used as the feedstock. This can be considered as another advantage of 2-MF-butanal route. It is interesting that Ni-WxC/C catalyst exhibited excellent catalytic performance and good stability in the hydrodeoxygenation of hydroxyalkylation/alkylation products, which made it a promising substitute for the noble metal catalysts. (C) 2013 Elsevier Ltd. All rights reserved.
语种英语
资助者1,1 ; 1,1 ; 1,1 ; 1,1
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WOS记录号WOS:000328512800001
引用统计
被引频次:40[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/119424
专题中国科学院大连化学物理研究所
通讯作者Zhang T(张涛)
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 10049, Peoples R China
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GB/T 7714
Li, Guangyi,Li, Ning,Yang, Jinfan,et al. Synthesis of renewable diesel with the 2-methylfuran, butanal and acetone derived from lignocellulose[J]. BIORESOURCE TECHNOLOGY,2013,134:66-72.
APA Li, Guangyi.,Li, Ning.,Yang, Jinfan.,Wang, Aiqin.,Wang, Xiaodong.,...&张涛.(2013).Synthesis of renewable diesel with the 2-methylfuran, butanal and acetone derived from lignocellulose.BIORESOURCE TECHNOLOGY,134,66-72.
MLA Li, Guangyi,et al."Synthesis of renewable diesel with the 2-methylfuran, butanal and acetone derived from lignocellulose".BIORESOURCE TECHNOLOGY 134(2013):66-72.
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