DICP OpenIR
Subject Area物理化学
Transalkylation of Phenol with Cumene on Zeolite Catalysts
Huang, Shengjun1; Zhang, Shuang1; Yu, Lili1,2; Liu, Zhenni1; Xin, Wenjie1; Xie, Sujuan1; Xu, Longya1; Xu LY(徐龙伢)
Source PublicationINDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
2013-08-14
DOI10.1021/ie401527f
Volume52Issue:32Pages:10996-11000
Indexed BySCI
Cooperation Status
SubtypeArticle
DepartmentDNL08
Funding ProjectDNL0804
Contribution Rank待补充
WOS HeadingsScience & Technology ; Technology
Funding Organization1,1 ; 1,1 ; 1,1 ; 1,1
WOS SubjectEngineering, Chemical
WOS Research AreaEngineering
WOS KeywordAL-MCM-41 MOLECULAR-SIEVES ; VAPOR-PHASE ISOPROPYLATION ; ZSM-5 ; ALKYLATION ; ACIDITY
AbstractLiquid-phase transalkylation of phenol with cumene was studied over various zeolites. Among the evaluated catalysts, ZSM-5 zeolites showed higher activities (ca. 50% phenol conversion) and usage efficiencies of isopropyl groups (ca. 80%) at 200 degrees C and 1.5 MPa. The higher catalytic performances of ZSM-5 zeolites are closely related to their channel structure and moderate cumene uptake capacities. It has been shown that the activities are related to the strong acidity of ZSM-5 zeolites. The passivation of external acid sites on ZSM-5 zeolite enhances the selectivity for para-isopropylphenol.
Language英语
Funding Organization1,1 ; 1,1 ; 1,1 ; 1,1
URL查看原文
WOS IDWOS:000323240900014
Citation statistics
Cited Times:1[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/119436
Collection中国科学院大连化学物理研究所
Corresponding AuthorXu LY(徐龙伢)
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Huang, Shengjun,Zhang, Shuang,Yu, Lili,et al. Transalkylation of Phenol with Cumene on Zeolite Catalysts[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2013,52(32):10996-11000.
APA Huang, Shengjun.,Zhang, Shuang.,Yu, Lili.,Liu, Zhenni.,Xin, Wenjie.,...&徐龙伢.(2013).Transalkylation of Phenol with Cumene on Zeolite Catalysts.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,52(32),10996-11000.
MLA Huang, Shengjun,et al."Transalkylation of Phenol with Cumene on Zeolite Catalysts".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 52.32(2013):10996-11000.
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