中国科学院大连化学物理研究所机构知识库
Advanced  
DICP OpenIR  > 中国科学院大连化学物理研究所  > 期刊论文
学科主题: 物理化学
题名: Synthesis of functionalized 2-pyridones via Michael addition and cyclization reaction of amines, alkynes and dialkyl acetylene dicarboxylates
作者: Chong, Qinglei1;  Xin, Xiaoyi1;  Wang, Chunxiang1;  Wu, Fan1;  Wan, Boshun1
通讯作者: 万伯顺
刊名: RSC ADVANCES
发表日期: 2013
DOI: 10.1039/c3ra43189d
卷: 3, 期:44, 页:21222-21226
收录类别: SCI
合作性质: 
文章类型: Article
部门归属: 2
项目归属: 202
产权排名: 待补充
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
资助者: 1,1
研究领域[WOS]: Chemistry
英文摘要: The Michael addition and three-component cyclization reaction of amines, alkynes and dialkyl acetylene dicarboxylates to form pyridones has been developed. Aliphatic amines and aromatic amines could selectively be converted into N-alkyl-disubstituted 2-pyridones and N-aryl-trisubstituted 2-pyridones with good yields in the presence of wet ethanol, which means a suitable amount of water is required for this reaction. The Michael addition and cyclization reaction process was confirmed through deuterium-labeling experiments, intermediates isolation and control experiments.
关键词[WOS]: RING-FUSED 2-PYRIDONES ;  REGIOSELECTIVE SYNTHESIS ;  PYRIDONE ALKALOIDS ;  DERIVATIVES ;  MECHANISM ;  TRANSFORMATIONS ;  CYCLOADDITION ;  HYDROLYSIS ;  SCAFFOLDS ;  MIGRATION
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000326056600005
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/119481
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

Files in This Item: Download All
File Name/ File Size Content Type Version Access License
2013pmNhjIGdgJ.PDF(711KB)----开放获取View Download

作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

Recommended Citation:
Chong, Qinglei,Xin, Xiaoyi,Wang, Chunxiang,et al. Synthesis of functionalized 2-pyridones via Michael addition and cyclization reaction of amines, alkynes and dialkyl acetylene dicarboxylates[J]. RSC ADVANCES,2013,3(44):21222-21226.
Service
 Recommend this item
 Sava as my favorate item
 Show this item's statistics
 Export Endnote File
Google Scholar
 Similar articles in Google Scholar
 [Chong, Qinglei]'s Articles
 [Xin, Xiaoyi]'s Articles
 [Wang, Chunxiang]'s Articles
CSDL cross search
 Similar articles in CSDL Cross Search
 [Chong, Qinglei]‘s Articles
 [Xin, Xiaoyi]‘s Articles
 [Wang, Chunxiang]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
  Add to CiteULike  Add to Connotea  Add to Del.icio.us  Add to Digg  Add to Reddit 
文件名: 2013pmNhjIGdgJ.PDF
格式: Adobe PDF
此文件暂不支持浏览
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace