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学科主题: 物理化学
题名: Direct synthesis of phenol from benzene catalyzed by multi-V-POMs complex
作者: Yang, Hua1, 2, 3;  Wu, Qing4;  Li, Jun1, 2;  Dai, Wen1, 2, 3;  Zhang, Hengyun1, 2;  Lu, Dan5;  Gao, Shuang1, 2;  You, Wansheng4
通讯作者: 高爽 ;  Wansheng You
关键词: Heteropolymolybdates ;  Vanadium-containing cation ;  Benzene ;  Phenol ;  H2O2
刊名: APPLIED CATALYSIS A-GENERAL
发表日期: 2013-04-24
DOI: 10.1016/j.apcata.2013.03.009
卷: 457, 页:21-25
收录类别: SCI
合作性质: 
文章类型: Article
部门归属: DNL08
项目归属: DNL0806
产权排名: 待补充
WOS标题词: Science & Technology ;  Physical Sciences ;  Life Sciences & Biomedicine
类目[WOS]: Chemistry, Physical ;  Environmental Sciences
资助者: 1,1
研究领域[WOS]: Chemistry ;  Environmental Sciences & Ecology
英文摘要: A novel catalyst, [Mo2V2O9(bpy)(6)][PMo11VO40], was synthesized by the self-assembling of [PMo11VO40](4-) and [Mo2V2O9(bpy)(6)](4+) unit and characterized by elemental analyses, TG, IR, X-ray powder diffraction and X-ray single crystal diffraction. [Mo2V2O9(bpy)(6)][PMo11VO40] with multi-isolated active sites showed good catalytic activities for hydroxylation of benzene to phenol. A high yield of phenol (25.5%) with selectivity to phenol of 90.7% was obtained using H2O2 as oxidant. The catalyst can be recycled for 5 times while its structure was unchanged and its catalytic activity was maintained. (c) 2013 Elsevier B.V. All rights reserved.
关键词[WOS]: VANADIUM-SUBSTITUTED HETEROPOLYMOLYBDATES ;  HYDROGEN-PEROXIDE ;  SELECTIVE HYDROXYLATION ;  DIRECT OXIDATION ;  ACID ;  OXYGEN ;  OXIDE ;  EPOXIDATION ;  METALS ;  SYSTEM
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000319791000003
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/119504
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, DICP, Dalian 116023, Peoples R China
2.Dalian Natl Lab Clean Energy DNL, Dalian 116023, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
4.Liaoning Normal Univ, Inst Chem Functionalized Mat, Dalian 116029, Peoples R China
5.Yanshan Univ, Liren Coll, Qinhuangdao 066004, Peoples R China

Recommended Citation:
Yang, Hua,Wu, Qing,Li, Jun,et al. Direct synthesis of phenol from benzene catalyzed by multi-V-POMs complex[J]. APPLIED CATALYSIS A-GENERAL,2013,457:21-25.
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