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学科主题: 物理化学
题名: Ultrafast photoinduced dynamics of halogenated cyclopentadienes: observation of geminate charge-transfer complexes in solution
作者: Wolf, T. J. A.1, 2;  Schalk, O.3, 4, 5;  Radloff, R.1, 2;  Wu, G.3, 6;  Lang, P.4;  Stolow, A.3;  Unterreiner, A. -N.1, 2
通讯作者: T. J. A. Wolf ;  A.-N. Unterreiner
刊名: PHYSICAL CHEMISTRY CHEMICAL PHYSICS
发表日期: 2013
DOI: 10.1039/c3cp44295k
卷: 15, 期:18, 页:6673-6683
收录类别: SCI
合作性质: 
文章类型: Article
部门归属: 11
项目归属: 1102
产权排名: 待补充
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Physical ;  Physics, Atomic, Molecular & Chemical
资助者: 5,4
研究领域[WOS]: Chemistry ;  Physics
英文摘要: The photoinduced dynamics of the fully halogenated cyclopentadienes C5Cl6 and C5Br6 have been investigated in solution and gas phase by femtosecond time-resolved spectroscopy. Both in solution and in gas phase, homolytic dissociation into a halogen radical and a C5X5 (X = Cl, Br) radical was observed. In liquid phase, solvent-dependent formation of charge transfer complexes between geminate radicals was observed for the first time. These complexes were found to be surprisingly stable and offered the opportunity to follow the dynamics of specific radical pairs. In the case of C5Cl6 in trichloroethanol, a reaction of the chlorine radical with molecules from the solvent cage was observed.
关键词[WOS]: THE-IDENTITY APPROXIMATION ;  DENSITY-FUNCTIONAL THEORY ;  BROMINE ATOM COMPLEXES ;  BASIS-SETS ;  PROGRAM SYSTEM ;  EXCITED-STATES ;  CONICAL INTERSECTIONS ;  MOLECULAR-DYNAMICS ;  SPECTRA ;  CHLORINE
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000317866300011
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/119508
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Karlsruhe Inst Technol, Inst Phys Chem, D-76131 Karlsruhe, Germany
2.Karlsruhe Inst Technol, Ctr Funct Nanostruct, D-76131 Karlsruhe, Germany
3.Natl Res Council Canada, Ottawa, ON K1A 0R6, Canada
4.Univ Munich, Lehrstuhl BioMol Opt, D-80538 Munich, Germany
5.Stockholm Univ, AlbaNova Univ Ctr, SE-10691 Stockholm, Sweden
6.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Liaoning, Peoples R China

Recommended Citation:
Wolf, T. J. A.,Schalk, O.,Radloff, R.,et al. Ultrafast photoinduced dynamics of halogenated cyclopentadienes: observation of geminate charge-transfer complexes in solution[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS,2013,15(18):6673-6683.
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