DICP OpenIR
学科主题物理化学
Ultrafast photoinduced dynamics of halogenated cyclopentadienes: observation of geminate charge-transfer complexes in solution
Wolf, T. J. A.1,2; Schalk, O.3,4,5; Radloff, R.1,2; Wu, G.3,6; Lang, P.4; Stolow, A.3; Unterreiner, A. -N.1,2; T. J. A. Wolf; A.-N. Unterreiner
刊名PHYSICAL CHEMISTRY CHEMICAL PHYSICS
2013
DOI10.1039/c3cp44295k
15期:18页:6673-6683
收录类别SCI
合作性质
文章类型Article
部门归属11
项目归属1102
产权排名待补充
WOS标题词Science & Technology ; Physical Sciences
资助者5,4 ; 5,4 ; 5,4 ; 5,4
类目[WOS]Chemistry, Physical ; Physics, Atomic, Molecular & Chemical
研究领域[WOS]Chemistry ; Physics
关键词[WOS]THE-IDENTITY APPROXIMATION ; DENSITY-FUNCTIONAL THEORY ; BROMINE ATOM COMPLEXES ; BASIS-SETS ; PROGRAM SYSTEM ; EXCITED-STATES ; CONICAL INTERSECTIONS ; MOLECULAR-DYNAMICS ; SPECTRA ; CHLORINE
英文摘要The photoinduced dynamics of the fully halogenated cyclopentadienes C5Cl6 and C5Br6 have been investigated in solution and gas phase by femtosecond time-resolved spectroscopy. Both in solution and in gas phase, homolytic dissociation into a halogen radical and a C5X5 (X = Cl, Br) radical was observed. In liquid phase, solvent-dependent formation of charge transfer complexes between geminate radicals was observed for the first time. These complexes were found to be surprisingly stable and offered the opportunity to follow the dynamics of specific radical pairs. In the case of C5Cl6 in trichloroethanol, a reaction of the chlorine radical with molecules from the solvent cage was observed.
语种英语
资助者5,4 ; 5,4 ; 5,4 ; 5,4
原文出处查看原文
WOS记录号WOS:000317866300011
引用统计
被引频次:3[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/119508
专题中国科学院大连化学物理研究所
通讯作者T. J. A. Wolf; A.-N. Unterreiner
作者单位1.Karlsruhe Inst Technol, Inst Phys Chem, D-76131 Karlsruhe, Germany
2.Karlsruhe Inst Technol, Ctr Funct Nanostruct, D-76131 Karlsruhe, Germany
3.Natl Res Council Canada, Ottawa, ON K1A 0R6, Canada
4.Univ Munich, Lehrstuhl BioMol Opt, D-80538 Munich, Germany
5.Stockholm Univ, AlbaNova Univ Ctr, SE-10691 Stockholm, Sweden
6.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Liaoning, Peoples R China
推荐引用方式
GB/T 7714
Wolf, T. J. A.,Schalk, O.,Radloff, R.,et al. Ultrafast photoinduced dynamics of halogenated cyclopentadienes: observation of geminate charge-transfer complexes in solution[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS,2013,15(18):6673-6683.
APA Wolf, T. J. A..,Schalk, O..,Radloff, R..,Wu, G..,Lang, P..,...&A.-N. Unterreiner.(2013).Ultrafast photoinduced dynamics of halogenated cyclopentadienes: observation of geminate charge-transfer complexes in solution.PHYSICAL CHEMISTRY CHEMICAL PHYSICS,15(18),6673-6683.
MLA Wolf, T. J. A.,et al."Ultrafast photoinduced dynamics of halogenated cyclopentadienes: observation of geminate charge-transfer complexes in solution".PHYSICAL CHEMISTRY CHEMICAL PHYSICS 15.18(2013):6673-6683.
条目包含的文件
文件名称/大小 文献类型 版本类型 开放类型 使用许可
2013RBDwfOz2E8.PDF(4945KB) 开放获取CC BY-NC-SA请求全文
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Wolf, T. J. A.]的文章
[Schalk, O.]的文章
[Radloff, R.]的文章
百度学术
百度学术中相似的文章
[Wolf, T. J. A.]的文章
[Schalk, O.]的文章
[Radloff, R.]的文章
必应学术
必应学术中相似的文章
[Wolf, T. J. A.]的文章
[Schalk, O.]的文章
[Radloff, R.]的文章
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。