DICP OpenIR
Subject Area物理化学
Ultrafast photoinduced dynamics of halogenated cyclopentadienes: observation of geminate charge-transfer complexes in solution
Wolf, T. J. A.1,2; Schalk, O.3,4,5; Radloff, R.1,2; Wu, G.3,6; Lang, P.4; Stolow, A.3; Unterreiner, A. -N.1,2; T. J. A. Wolf; A.-N. Unterreiner
Source PublicationPHYSICAL CHEMISTRY CHEMICAL PHYSICS
2013
DOI10.1039/c3cp44295k
Volume15Issue:18Pages:6673-6683
Indexed BySCI
Cooperation Status
SubtypeArticle
Department11
Funding Project1102
Contribution Rank待补充
WOS HeadingsScience & Technology ; Physical Sciences
Funding Organization5,4 ; 5,4 ; 5,4 ; 5,4
WOS SubjectChemistry, Physical ; Physics, Atomic, Molecular & Chemical
WOS Research AreaChemistry ; Physics
WOS KeywordTHE-IDENTITY APPROXIMATION ; DENSITY-FUNCTIONAL THEORY ; BROMINE ATOM COMPLEXES ; BASIS-SETS ; PROGRAM SYSTEM ; EXCITED-STATES ; CONICAL INTERSECTIONS ; MOLECULAR-DYNAMICS ; SPECTRA ; CHLORINE
AbstractThe photoinduced dynamics of the fully halogenated cyclopentadienes C5Cl6 and C5Br6 have been investigated in solution and gas phase by femtosecond time-resolved spectroscopy. Both in solution and in gas phase, homolytic dissociation into a halogen radical and a C5X5 (X = Cl, Br) radical was observed. In liquid phase, solvent-dependent formation of charge transfer complexes between geminate radicals was observed for the first time. These complexes were found to be surprisingly stable and offered the opportunity to follow the dynamics of specific radical pairs. In the case of C5Cl6 in trichloroethanol, a reaction of the chlorine radical with molecules from the solvent cage was observed.
Language英语
Funding Organization5,4 ; 5,4 ; 5,4 ; 5,4
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WOS IDWOS:000317866300011
Citation statistics
Cited Times:3[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/119508
Collection中国科学院大连化学物理研究所
Corresponding AuthorT. J. A. Wolf; A.-N. Unterreiner
Affiliation1.Karlsruhe Inst Technol, Inst Phys Chem, D-76131 Karlsruhe, Germany
2.Karlsruhe Inst Technol, Ctr Funct Nanostruct, D-76131 Karlsruhe, Germany
3.Natl Res Council Canada, Ottawa, ON K1A 0R6, Canada
4.Univ Munich, Lehrstuhl BioMol Opt, D-80538 Munich, Germany
5.Stockholm Univ, AlbaNova Univ Ctr, SE-10691 Stockholm, Sweden
6.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Liaoning, Peoples R China
Recommended Citation
GB/T 7714
Wolf, T. J. A.,Schalk, O.,Radloff, R.,et al. Ultrafast photoinduced dynamics of halogenated cyclopentadienes: observation of geminate charge-transfer complexes in solution[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS,2013,15(18):6673-6683.
APA Wolf, T. J. A..,Schalk, O..,Radloff, R..,Wu, G..,Lang, P..,...&A.-N. Unterreiner.(2013).Ultrafast photoinduced dynamics of halogenated cyclopentadienes: observation of geminate charge-transfer complexes in solution.PHYSICAL CHEMISTRY CHEMICAL PHYSICS,15(18),6673-6683.
MLA Wolf, T. J. A.,et al."Ultrafast photoinduced dynamics of halogenated cyclopentadienes: observation of geminate charge-transfer complexes in solution".PHYSICAL CHEMISTRY CHEMICAL PHYSICS 15.18(2013):6673-6683.
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