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学科主题: 物理化学
题名: LiCu2[BP2O8(OH)2]: a chiral open-framework copper borophosphate via spontaneous asymmetrical crystallization
作者: Yang, Miao1, 2;  Li, Xinjie1, 4;  Yu, Jihong3;  Zhu, Jingran3;  Liu, Xiaoxia4;  Chen, Genfu5, 6;  Yan, Yan3
通讯作者: 杨淼
刊名: DALTON TRANSACTIONS
发表日期: 2013
DOI: 10.1039/c3dt50591j
卷: 42, 期:18, 页:6298-6301
收录类别: SCI
合作性质: 
文章类型: Article
部门归属: 2,DNL12
项目归属: 207,DNL1202
产权排名: 待补充
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Inorganic & Nuclear
资助者: 1,1
研究领域[WOS]: Chemistry
英文摘要: A new chiral copper borophosphate, LiCu2[BP2O8(OH)(2)] ( 1), was crystallized from achiral inorganic raw materials in boric acid flux reaction. The structure features a 9-ring channel enclosed by triple right-handed helices. The bulk sample exhibits optical activity confirmed by circular dichroism (CD) spectra, indicating an interesting spontaneous resolution phenomenon.
关键词[WOS]: CRYSTAL-STRUCTURE ;  COORDINATION POLYMER ;  SYMMETRY-BREAKING ;  HELICAL CHAINS ;  CHANNELS ;  METALLOBOROPHOSPHATES ;  DEHYDRATION ;  TOPOLOGY ;  ZN ;  SR
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000317583000007
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/119572
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, China Ion Liquid Lab, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Natl Engn Lab Methanol Olefins, Dalian 116023, Peoples R China
3.Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China
4.Northeastern Univ, Dept Chem, Shenyang 110004, Peoples R China
5.Chinese Acad Sci, Natl Lab Superconduct, Inst Phys, Beijing 100190, Peoples R China
6.Chinese Acad Sci, Beijing Natl Lab Condensed Matter Phys, Beijing 100190, Peoples R China

Recommended Citation:
Yang, Miao,Li, Xinjie,Yu, Jihong,et al. LiCu2[BP2O8(OH)2]: a chiral open-framework copper borophosphate via spontaneous asymmetrical crystallization[J]. DALTON TRANSACTIONS,2013,42(18):6298-6301.
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