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学科主题: 物理化学
题名: Conversion of Glucose to 5-Hydroxymethylfurfural Catalyzed by Metal Halide in N,N-Dimethylacetamide
作者: Ren, Qiuhe1, 2, 3;  Huang, Yizheng1, 2;  Ma, Hong1, 2;  Wang, Feng1, 2;  Gao, Jin1, 2;  Xu, Jie1, 2
通讯作者: 徐杰
关键词: Glucose ;  Dehydration ;  Metal halide ;  5-Hydroxymethylfurfural
刊名: BIORESOURCES
发表日期: 2013
卷: 8, 期:2, 页:1563-1572
收录类别: SCI
合作性质: 
文章类型: Article
部门归属: DNl06
项目归属: DNL0601
产权排名: 待补充
WOS标题词: Science & Technology ;  Technology
类目[WOS]: Materials Science, Paper & Wood
资助者: 1,1
研究领域[WOS]: Materials Science
英文摘要: A simple strategy is reported for catalytic conversion of glucose to 5-hydroxymethylfurfural (HMF) over All(3) in N,N-dimethylacetamide (DMAC). When the reaction was conducted in DMAC at 120 degrees C for 15 min over All(3) catalyst, HMF was obtained with a yield of 52%. The reaction course was monitored by C-13 NMR spectroscopy and HPLC analysis. The results suggest that All(3) catalyzes the three consecutive reactions consisting of mutarotation of alpha-glucopyranose to beta-glucopyranose, isomerization of glucose to fructose, and dehydration of fructose to HMF.
关键词[WOS]: LIGNOCELLULOSIC BIOMASS ;  IONIC LIQUID ;  SOLID ACID ;  CHEMICALS ;  CHLORIDE ;  FUELS ;  WATER ;  HMF ;  FRUCTOSE ;  SOLVENTS
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000315386400008
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/119580
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100039, Peoples R China

Recommended Citation:
Ren, Qiuhe,Huang, Yizheng,Ma, Hong,et al. Conversion of Glucose to 5-Hydroxymethylfurfural Catalyzed by Metal Halide in N,N-Dimethylacetamide[J]. BIORESOURCES,2013,8(2):1563-1572.
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