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学科主题: 物理化学
题名: Microwave-assisted catalytic conversion of cellulose into 5-hydroxymethylfurfural in ionic liquids
作者: Liu, Bing1, 2;  Zhang, Zehui1, 2;  Zhao, Zongbao Kent3, 4
通讯作者: 赵宗保 ;  张泽会
关键词: Biomass ;  Cellulose ;  Zirconium chloride ;  5-Hydroxymethylfurfural ;  Ionic liquids ;  Microwave irradiation
刊名: CHEMICAL ENGINEERING JOURNAL
发表日期: 2013-01-15
DOI: 10.1016/j.cej.2012.11.019
卷: 215, 页:517-521
收录类别: SCI
合作性质: 
文章类型: Article
部门归属: 18
项目归属: 1816
产权排名: 待补充
WOS标题词: Science & Technology ;  Technology
类目[WOS]: Engineering, Environmental ;  Engineering, Chemical
资助者: 2,3
研究领域[WOS]: Engineering
英文摘要: Microwave-assisted direct conversion of cellulose into HMF in ionic liquids catalyzed by ZrCl4 has been investigated in search of an efficient and environment-friendly process. Firstly, some representative metal chlorides were used to catalyze the conversion of glucose into HMF, and it was demonstrated that ZrCl4 was superior to other catalysts. Then direct conversion of cellulose into HMF was catalyzed by ZrCl4 under microwave irradiation (MI). Under optimal conditions, a high HMF yield up to 51.4% was obtained from cellulose in 3.5 mm under MI at 400W. Controllable experiments indicated that both ionic liquids, MI and ZrCl4 showed synergetic effects on the efficient conversion of cellulose into HMF. This work provides a meaningful method for the conversion of carbohydrates into fine chemicals. (C) 2012 Elsevier B.V. All rights reserved.
关键词[WOS]: ACID ;  HYDROLYSIS ;  EFFICIENT ;  GLUCOSE ;  IMIDAZOLIUM ;  CHEMISTRY ;  BIOMASS ;  WATER
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000316032100064
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/119606
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.South Cent Univ Nationalities, Coll Chem & Mat Sci, Key Lab Catalysis & Mat Sci State Ethn Affairs Co, Wuhan 430074, Peoples R China
2.South Cent Univ Nationalities, Coll Chem & Mat Sci, Minist Educ, Wuhan 430074, Peoples R China
3.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
4.Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China

Recommended Citation:
Liu, Bing,Zhang, Zehui,Zhao, Zongbao Kent. Microwave-assisted catalytic conversion of cellulose into 5-hydroxymethylfurfural in ionic liquids[J]. CHEMICAL ENGINEERING JOURNAL,2013,215:517-521.
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