中国科学院大连化学物理研究所机构知识库
Advanced  
DICP OpenIR  > 中国科学院大连化学物理研究所  > 期刊论文
学科主题: 物理化学
题名: A Dication Cross-Linked Composite Anion-Exchange Membrane for All-Vanadium Flow Battery Applications
作者: Zhang, Fengxiang1;  Zhang, Huamin1;  Qu, Chao1
通讯作者: 张凤祥 ;  张华民
关键词: anion exchange ;  electrochemistry ;  membranes ;  synthesis design ;  vanadium batteries
刊名: CHEMSUSCHEM
发表日期: 2013-12-01
DOI: 10.1002/cssc.201300560
卷: 6, 期:12, 页:2290-2298
收录类别: SCI
合作性质: 
文章类型: Article
部门归属: DNL17
项目归属: DNL17
产权排名: 待补充
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
资助者: 1,1
研究领域[WOS]: Chemistry
英文摘要: We report the fabrication and properties of a high-performance, inexpensive, composite, anion-exchange membrane (AEM) for an all-vanadium flow battery (VFB) application. The AEM was fabricated by dication cross-linking without the involvement of trimethylamine, and shows well-balanced anion conductivity and robustness due to imidazolium and imidazolium-ammonium functionalities, as well as a concomitantly achieved semi-interpenetrating network structure. The VFB single cell yielded a Coulombic efficiency of 99% and an energy efficiency of 84% at 80mAcm(-2), and operated for over 900 charge/discharge cycles. This work demonstrates the combined use of several favorable AEM design rationales, such as incorporating abundant and efficient anion-exchange groups, constructing a swelling- and oxidation-resistant structure, and facile fabrication; it provides an effective way of developing high-performance, low-cost AEMs for VFB applications.
关键词[WOS]: FUEL-CELL APPLICATIONS ;  SEMIINTERPENETRATING POLYMER NETWORK ;  CONDUCTIVE MEMBRANES ;  NAFION MEMBRANE ;  REDOX BATTERY ;  PERMEABILITY ;  PERFORMANCE ;  METHACRYLATE ;  STYRENE ;  GRAFT
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000328218400015
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/119610
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

Files in This Item: Download All
File Name/ File Size Content Type Version Access License
2013vYzKmB1ObI.PDF(1892KB)----开放获取View Download

作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Ctr Energy Storage Technol, Dalian 116023, Peoples R China

Recommended Citation:
Zhang, Fengxiang,Zhang, Huamin,Qu, Chao. A Dication Cross-Linked Composite Anion-Exchange Membrane for All-Vanadium Flow Battery Applications[J]. CHEMSUSCHEM,2013,6(12):2290-2298.
Service
 Recommend this item
 Sava as my favorate item
 Show this item's statistics
 Export Endnote File
Google Scholar
 Similar articles in Google Scholar
 [Zhang, Fengxiang]'s Articles
 [Zhang, Huamin]'s Articles
 [Qu, Chao]'s Articles
CSDL cross search
 Similar articles in CSDL Cross Search
 [Zhang, Fengxiang]‘s Articles
 [Zhang, Huamin]‘s Articles
 [Qu, Chao]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
  Add to CiteULike  Add to Connotea  Add to Del.icio.us  Add to Digg  Add to Reddit 
文件名: 2013vYzKmB1ObI.PDF
格式: Adobe PDF
此文件暂不支持浏览
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace