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学科主题: 物理化学
题名: Recent progress in methane dehydroaromatization: From laboratory curiosities to promising technology
作者: 马书启1, 2;  Guo, Xiaoguang1;  Zhao, Lingxiao1;  Scott, Susannah3, 4;  Bao, Xinhe1
通讯作者: 包信和
关键词: direct conversion ;  methane ;  methane dehydroaromatization ;  Mo-based catalyst
刊名: JOURNAL OF ENERGY CHEMISTRY
发表日期: 2013
卷: 22, 期:1, 页:1-20
收录类别: SCI
合作性质: 
文章类型: Review
部门归属: 5
项目归属: 502
产权排名: 待补充
WOS标题词: Science & Technology ;  Physical Sciences ;  Technology
类目[WOS]: Chemistry, Applied ;  Chemistry, Physical ;  Energy & Fuels ;  Engineering, Chemical
资助者: 1,1
研究领域[WOS]: Chemistry ;  Energy & Fuels ;  Engineering
英文摘要: Direct conversion of methane to benzene or other valuable chemicals is a very promising process for the efficient application of natural gas. Compared with conversion processes that require oxidants, non-oxidative direct conversion is more attractive due to high selectivity to the target product. In this paper, an alternative route for methane dehydrogenation and selective conversion to benzene and hydrogen without the participation of oxygen is discussed. A brief review of the catalysts used in methane dehydroaromatization (MDA) is first given, followed by our current understanding of the location and the active phase of Mo species, the reaction mechanism, the mechanism of carbonaceous deposit and the deactivation of Mo/zeolite catalysts are systematically discussed. Ways to improve the catalytic activity and stability are described in detail based on catalyst and reaction as well as reactor design. Future prospects for methane dehydroaromatization process are also presented.
关键词[WOS]: MO-BASED CATALYSTS ;  HYDROTHERMAL POST-SYNTHESIS ;  BRONSTED ACID SITES ;  TEMPERATURE NONOXIDATIVE ACTIVATION ;  GALLOALUMINOSILICATE MFI ZEOLITE ;  IMPREGNATED HZSM-5 CATALYSTS ;  HIGHLY STABLE PERFORMANCE ;  SUPERSONIC JET EXPANSION ;  SINGLE-PASS CONVERSION ;  MO-95 NMR-SPECTROSCOPY
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000318050700002
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/119624
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China
2.Henan Polytech Univ, Sch Phys & Chem, Jiaozuo 454000, Henan, Peoples R China
3.Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA
4.Univ Calif Santa Barbara, Dept Chem Engn, Santa Barbara, CA 93106 USA

Recommended Citation:
Ma, Shuqi,Guo, Xiaoguang,Zhao, Lingxiao,et al. Recent progress in methane dehydroaromatization: From laboratory curiosities to promising technology[J]. JOURNAL OF ENERGY CHEMISTRY,2013,22(1):1-20.
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