DICP OpenIR
Subject Area物理化学
Aerobic oxidation of primary aliphatic alcohols over bismuth oxide supported platinum catalysts in water
Lu, Tianliang1,2; Du, Zhongtian1; Liu, Junxia1,2; Ma, Hong1; Xu, Jie1; Xu J(徐杰)
Source PublicationGREEN CHEMISTRY
2013
DOI10.1039/c3gc40730f
Volume15Issue:8Pages:2215-2221
Indexed BySCI
Cooperation Status
SubtypeArticle
DepartmentDNL06
Funding ProjectDNL0601
Contribution Rank待补充
WOS HeadingsScience & Technology ; Physical Sciences
Funding Organization1,1 ; 1,1 ; 1,1 ; 1,1
WOS SubjectChemistry, Multidisciplinary
WOS Research AreaChemistry
WOS KeywordSELECTIVE OXIDATION ; METAL-CATALYSTS ; ORGANIC-CHEMISTRY ; MOLECULAR-OXYGEN ; GLYCEROL ; GREEN ; NANOPARTICLES ; DEACTIVATION ; TEMPERATURE ; ALDEHYDES
AbstractCatalytic oxidation of non-activated aliphatic alcohols with molecular oxygen is rather challenging, especially in an aqueous medium in the absence of an additional base. Bismuth is usually used as a promoter of platinum-based catalysts. In this work, bismuth oxide was explored as a support, and Pt-0 nanoparticles supported on bismuth oxide (Pt/Bi2O3) exhibited high activity for aerobic oxidation of n-butanol using water as a solvent in the absence of an additional base under optimized conditions. Besides n-butanol, liquid primary aliphatic alcohols with low solubility in water could also be smoothly oxidized into the corresponding carbonyl compounds with molecular oxygen. Pt/Bi2O3 reduced by H-2 at about 200 degrees C showed the highest activity for aerobic oxidation of n-butanol. At this temperature, platinum oxide was reduced to Pt-0 and bismuth oxide could be reduced partially which might change the surface property of bismuth oxide.
Language英语
Funding Organization1,1 ; 1,1 ; 1,1 ; 1,1
URL查看原文
WOS IDWOS:000322121400026
Citation statistics
Cited Times:44[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/119670
Collection中国科学院大连化学物理研究所
Corresponding AuthorXu J(徐杰)
Affiliation1.Chinese Acad Sci, State Key Lab Catalysis, Dalian Natl Lab Clean Energy, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Lu, Tianliang,Du, Zhongtian,Liu, Junxia,et al. Aerobic oxidation of primary aliphatic alcohols over bismuth oxide supported platinum catalysts in water[J]. GREEN CHEMISTRY,2013,15(8):2215-2221.
APA Lu, Tianliang,Du, Zhongtian,Liu, Junxia,Ma, Hong,Xu, Jie,&徐杰.(2013).Aerobic oxidation of primary aliphatic alcohols over bismuth oxide supported platinum catalysts in water.GREEN CHEMISTRY,15(8),2215-2221.
MLA Lu, Tianliang,et al."Aerobic oxidation of primary aliphatic alcohols over bismuth oxide supported platinum catalysts in water".GREEN CHEMISTRY 15.8(2013):2215-2221.
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