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学科主题物理化学
Aerobic oxidation of primary aliphatic alcohols over bismuth oxide supported platinum catalysts in water
Lu, Tianliang1,2; Du, Zhongtian1; Liu, Junxia1,2; Ma, Hong1; Xu, Jie1; Xu J(徐杰)
刊名GREEN CHEMISTRY
2013
DOI10.1039/c3gc40730f
15期:8页:2215-2221
收录类别SCI
合作性质
文章类型Article
部门归属DNL06
项目归属DNL0601
产权排名待补充
WOS标题词Science & Technology ; Physical Sciences
资助者1,1 ; 1,1 ; 1,1 ; 1,1
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]SELECTIVE OXIDATION ; METAL-CATALYSTS ; ORGANIC-CHEMISTRY ; MOLECULAR-OXYGEN ; GLYCEROL ; GREEN ; NANOPARTICLES ; DEACTIVATION ; TEMPERATURE ; ALDEHYDES
英文摘要Catalytic oxidation of non-activated aliphatic alcohols with molecular oxygen is rather challenging, especially in an aqueous medium in the absence of an additional base. Bismuth is usually used as a promoter of platinum-based catalysts. In this work, bismuth oxide was explored as a support, and Pt-0 nanoparticles supported on bismuth oxide (Pt/Bi2O3) exhibited high activity for aerobic oxidation of n-butanol using water as a solvent in the absence of an additional base under optimized conditions. Besides n-butanol, liquid primary aliphatic alcohols with low solubility in water could also be smoothly oxidized into the corresponding carbonyl compounds with molecular oxygen. Pt/Bi2O3 reduced by H-2 at about 200 degrees C showed the highest activity for aerobic oxidation of n-butanol. At this temperature, platinum oxide was reduced to Pt-0 and bismuth oxide could be reduced partially which might change the surface property of bismuth oxide.
语种英语
资助者1,1 ; 1,1 ; 1,1 ; 1,1
原文出处查看原文
WOS记录号WOS:000322121400026
引用统计
被引频次:40[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/119670
专题中国科学院大连化学物理研究所
通讯作者Xu J(徐杰)
作者单位1.Chinese Acad Sci, State Key Lab Catalysis, Dalian Natl Lab Clean Energy, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
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GB/T 7714
Lu, Tianliang,Du, Zhongtian,Liu, Junxia,et al. Aerobic oxidation of primary aliphatic alcohols over bismuth oxide supported platinum catalysts in water[J]. GREEN CHEMISTRY,2013,15(8):2215-2221.
APA Lu, Tianliang,Du, Zhongtian,Liu, Junxia,Ma, Hong,Xu, Jie,&徐杰.(2013).Aerobic oxidation of primary aliphatic alcohols over bismuth oxide supported platinum catalysts in water.GREEN CHEMISTRY,15(8),2215-2221.
MLA Lu, Tianliang,et al."Aerobic oxidation of primary aliphatic alcohols over bismuth oxide supported platinum catalysts in water".GREEN CHEMISTRY 15.8(2013):2215-2221.
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