中国科学院大连化学物理研究所机构知识库
Advanced  
DICP OpenIR  > 中国科学院大连化学物理研究所  > 期刊论文
学科主题: 物理化学
题名: Aerobic oxidation of primary aliphatic alcohols over bismuth oxide supported platinum catalysts in water
作者: Lu, Tianliang1, 2;  Du, Zhongtian1;  Liu, Junxia1, 2;  Ma, Hong1;  Xu, Jie1
通讯作者: 徐杰
刊名: GREEN CHEMISTRY
发表日期: 2013
DOI: 10.1039/c3gc40730f
卷: 15, 期:8, 页:2215-2221
收录类别: SCI
合作性质: 
文章类型: Article
部门归属: DNL06
项目归属: DNL0601
产权排名: 待补充
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
资助者: 1,1
研究领域[WOS]: Chemistry
英文摘要: Catalytic oxidation of non-activated aliphatic alcohols with molecular oxygen is rather challenging, especially in an aqueous medium in the absence of an additional base. Bismuth is usually used as a promoter of platinum-based catalysts. In this work, bismuth oxide was explored as a support, and Pt-0 nanoparticles supported on bismuth oxide (Pt/Bi2O3) exhibited high activity for aerobic oxidation of n-butanol using water as a solvent in the absence of an additional base under optimized conditions. Besides n-butanol, liquid primary aliphatic alcohols with low solubility in water could also be smoothly oxidized into the corresponding carbonyl compounds with molecular oxygen. Pt/Bi2O3 reduced by H-2 at about 200 degrees C showed the highest activity for aerobic oxidation of n-butanol. At this temperature, platinum oxide was reduced to Pt-0 and bismuth oxide could be reduced partially which might change the surface property of bismuth oxide.
关键词[WOS]: SELECTIVE OXIDATION ;  METAL-CATALYSTS ;  ORGANIC-CHEMISTRY ;  MOLECULAR-OXYGEN ;  GLYCEROL ;  GREEN ;  NANOPARTICLES ;  DEACTIVATION ;  TEMPERATURE ;  ALDEHYDES
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000322121400026
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/119670
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

Files in This Item:
File Name/ File Size Content Type Version Access License
2013z3lrnG54gX.PDF(1478KB)----开放获取View 联系获取全文

作者单位: 1.Chinese Acad Sci, State Key Lab Catalysis, Dalian Natl Lab Clean Energy, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China

Recommended Citation:
Lu, Tianliang,Du, Zhongtian,Liu, Junxia,et al. Aerobic oxidation of primary aliphatic alcohols over bismuth oxide supported platinum catalysts in water[J]. GREEN CHEMISTRY,2013,15(8):2215-2221.
Service
 Recommend this item
 Sava as my favorate item
 Show this item's statistics
 Export Endnote File
Google Scholar
 Similar articles in Google Scholar
 [Lu, Tianliang]'s Articles
 [Du, Zhongtian]'s Articles
 [Liu, Junxia]'s Articles
CSDL cross search
 Similar articles in CSDL Cross Search
 [Lu, Tianliang]‘s Articles
 [Du, Zhongtian]‘s Articles
 [Liu, Junxia]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
  Add to CiteULike  Add to Connotea  Add to Del.icio.us  Add to Digg  Add to Reddit 
文件名: 2013z3lrnG54gX.PDF
格式: Adobe PDF
此文件暂不支持浏览
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace