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学科主题: 物理化学
题名: Rapid and Efficient Functionalized Ionic Liquid-Catalyzed Aldol Condensation Reactions Associated with Microwave Irradiation
作者: Wang, Chang1;  Liu, Jing1;  Leng, Wenguang1;  Gao, Yanan1
通讯作者: 高艳安
关键词: aldol reaction ;  microwave ;  green chemistry ;  ionic liquid
刊名: INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
发表日期: 2014
DOI: 10.3390/ijms15011284
卷: 15, 期:1, 页:1284-1299
收录类别: SCI
合作性质: 
文章类型: Article
部门归属: 2
项目归属: 207
产权排名: 待补充
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
资助者: 1,1
研究领域[WOS]: Chemistry
英文摘要: Five quaternary ammonium ionic liquid (IL) and two tetrabutylphosphonium ILs were prepared and characterized. An environmentally benign and convenient functionalized ionic liquid catalytic system was thus explored in the aldol condensation reactions of aromatic aldehydes with acetone. The aldol reactions proceeded more efficiently through microwave-assisted heating than through conventional thermal heating. The yield of products obtained under microwave heating for 30 min was approximately 90%, and the ILs can be recovered and reused at least five times without apparent loss of activity. In addition, this catalytic system can be successfully extended to the Henry reactions.
关键词[WOS]: CROSS-ALDOL ;  ORGANIC-SYNTHESIS ;  GREEN CHEMISTRY ;  CO2 CAPTURE ;  ALDEHYDES ;  KETONES ;  SOLVENT ;  MEDIA ;  CYCLOALKANONES ;  KNOEVENAGEL
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000335776100076
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/119703
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

Recommended Citation:
Wang, Chang,Liu, Jing,Leng, Wenguang,et al. Rapid and Efficient Functionalized Ionic Liquid-Catalyzed Aldol Condensation Reactions Associated with Microwave Irradiation[J]. INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES,2014,15(1):1284-1299.
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