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学科主题物理化学
Co(II) coordinated metal-organic framework: An efficient catalyst for heterogeneous aerobic olefins epoxidation
Sha, Sha1,2,3; Yang, Hua1,2; Li, Jun1,2; Zhuang, Changfu1,2; Gao, Shuang1,2; Liu, Shuxia3; Gao S(高爽); Shuxia Liu
关键词Mofs Oxygen Epoxidation Olefin
刊名CATALYSIS COMMUNICATIONS
2014-01-05
DOI10.1016/j.catcom.2013.09.014
43页:146-150
收录类别SCI
合作性质
文章类型Article
部门归属DNL08
项目归属DNL0806
产权排名待补充
WOS标题词Science & Technology ; Physical Sciences
资助者1,1 ; 1,1 ; 1,1 ; 1,1
类目[WOS]Chemistry, Physical
研究领域[WOS]Chemistry
关键词[WOS]MOLECULAR-OXYGEN ; HYDROGEN-PEROXIDE ; COMPLEX ; ALKENES ; OXIDATION ; DIOXYGEN ; STYRENE
英文摘要An 8-connected, linear trinuclear cluster-based microporous metal organic framework (NH4)(2)[Co-3(Ina)(BDC)(3)(HCOO)] (denoted as CO(3)InaBDC(3), Ina = isonicotinate and BDC = 1,4-benzenedicarboxylate, CCDC is 935147) had been successfully synthesized by a facile hydrothermal synthesis method. The compound was extended through BDC linkers breadthwise and Ina linkers lengthways to the highly-connected framework. The CO(3)InaBDC(3) was characterized through FT-IR, N-2 adsorption, XRD, TGA and SEM, and its characteristic structure was elucidated by single crystal X-ray diffraction. Using O-2 as oxidant, the CO(3)InaBDC(3) was investigated as a good performed heterogeneous catalytic material for cydooctene epoxidation. An extremely high turnover frequency (1370 h(-1)) for epoxycyclooctane was achieved, and CO(3)InaBDC(3) exhibited excellent stabilities in 5 recycles without any loss of its catalytic performance. (C) 2013 Elsevier B.V. All rights reserved.
语种英语
资助者1,1 ; 1,1 ; 1,1 ; 1,1
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WOS记录号WOS:000328527000032
引用统计
被引频次:15[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/119742
专题中国科学院大连化学物理研究所
通讯作者Gao S(高爽); Shuxia Liu
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
3.NE Normal Univ, Dept Chem, Key Lab Polyoxometalate Sci, Changchun 130024, Peoples R China
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GB/T 7714
Sha, Sha,Yang, Hua,Li, Jun,et al. Co(II) coordinated metal-organic framework: An efficient catalyst for heterogeneous aerobic olefins epoxidation[J]. CATALYSIS COMMUNICATIONS,2014,43:146-150.
APA Sha, Sha.,Yang, Hua.,Li, Jun.,Zhuang, Changfu.,Gao, Shuang.,...&Shuxia Liu.(2014).Co(II) coordinated metal-organic framework: An efficient catalyst for heterogeneous aerobic olefins epoxidation.CATALYSIS COMMUNICATIONS,43,146-150.
MLA Sha, Sha,et al."Co(II) coordinated metal-organic framework: An efficient catalyst for heterogeneous aerobic olefins epoxidation".CATALYSIS COMMUNICATIONS 43(2014):146-150.
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