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学科主题: 物理化学
题名: Co(II) coordinated metal-organic framework: An efficient catalyst for heterogeneous aerobic olefins epoxidation
作者: Sha, Sha1, 2, 3;  Yang, Hua1, 2;  Li, Jun1, 2;  Zhuang, Changfu1, 2;  Gao, Shuang1, 2;  Liu, Shuxia3
通讯作者: 高爽 ;  Shuxia Liu
关键词: MOFs ;  Oxygen ;  Epoxidation ;  Olefin
刊名: CATALYSIS COMMUNICATIONS
发表日期: 2014-01-05
DOI: 10.1016/j.catcom.2013.09.014
卷: 43, 页:146-150
收录类别: SCI
合作性质: 
文章类型: Article
部门归属: DNL08
项目归属: DNL0806
产权排名: 待补充
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Physical
资助者: 1,1
研究领域[WOS]: Chemistry
英文摘要: An 8-connected, linear trinuclear cluster-based microporous metal organic framework (NH4)(2)[Co-3(Ina)(BDC)(3)(HCOO)] (denoted as CO(3)InaBDC(3), Ina = isonicotinate and BDC = 1,4-benzenedicarboxylate, CCDC is 935147) had been successfully synthesized by a facile hydrothermal synthesis method. The compound was extended through BDC linkers breadthwise and Ina linkers lengthways to the highly-connected framework. The CO(3)InaBDC(3) was characterized through FT-IR, N-2 adsorption, XRD, TGA and SEM, and its characteristic structure was elucidated by single crystal X-ray diffraction. Using O-2 as oxidant, the CO(3)InaBDC(3) was investigated as a good performed heterogeneous catalytic material for cydooctene epoxidation. An extremely high turnover frequency (1370 h(-1)) for epoxycyclooctane was achieved, and CO(3)InaBDC(3) exhibited excellent stabilities in 5 recycles without any loss of its catalytic performance. (C) 2013 Elsevier B.V. All rights reserved.
关键词[WOS]: MOLECULAR-OXYGEN ;  HYDROGEN-PEROXIDE ;  COMPLEX ;  ALKENES ;  OXIDATION ;  DIOXYGEN ;  STYRENE
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000328527000032
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/119742
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
3.NE Normal Univ, Dept Chem, Key Lab Polyoxometalate Sci, Changchun 130024, Peoples R China

Recommended Citation:
Sha, Sha,Yang, Hua,Li, Jun,et al. Co(II) coordinated metal-organic framework: An efficient catalyst for heterogeneous aerobic olefins epoxidation[J]. CATALYSIS COMMUNICATIONS,2014,43:146-150.
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