DICP OpenIR
Subject Area物理化学
An investigation into low-lying electronic states of HCS2 via threshold photoelectron imaging
Qin, Zhengbo; Cong, Ran; Liu, Zhiling; Xie, Hua; Tang, Zichao; Fan, Hongjun; Tang ZC(唐紫超); Fan HJ(樊红军)
Source PublicationJOURNAL OF CHEMICAL PHYSICS
2014-06-07
ISSN1089-7690
DOI10.1063/1.4879808
Volume140Issue:21Pages:214318
Indexed BySCI
Cooperation Status
SubtypeArticle
Department11
Funding Project1108,1102
Contribution Rank待补充
WOS HeadingsScience & Technology ; Physical Sciences
Funding Organization1,1 ; 1,1 ; 1,1 ; 1,1
WOS SubjectPhysics, Atomic, Molecular & Chemical
WOS Research AreaPhysics
WOS KeywordTANDEM MASS-SPECTROMETRY ; POTENTIAL-ENERGY SURFACE ; NEGATIVE-IONS ; INFRARED-SPECTRA ; CARBON-DISULFIDE ; SPECTROSCOPY ; HCO2 ; DENSITY ; ANIONS ; THIOFORMALDEHYDE
AbstractLow-energy photoelectron imaging spectra of HCS(2)(-)are reported for the first time. Vibrationally resolved photodetachment transitions from the ground state of HCS2- to the ground state and low-lying excited states of HCS2 are observed. Combined with the ab intio calculations and Franck-Condon simulations, well-resolved vibrational spectra demonstrate definitive evidence for the resolution of the ground-state and excited states of HCS2 radical in the gaseous phase. The ground state and two low-lying excited states of HCS2 radical are assigned as B-2(2), (2)A(2), and (2)A(1) states, respectively. The adiabatic electron affinity is determined to be 2.910 +/- 0.007 eV. And the term energies of the excited states, T-0 = 0.451 +/- 0.009 eV and 0.553 +/- 0.009 eV, are directly measured from the experimental data, respectively. Angular filtering photoelectron spectra are carried out to assist in the spectral band assignment. (C) 2014 AIP Publishing LLC.
Language英语
Funding Organization1,1 ; 1,1 ; 1,1 ; 1,1
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WOS IDWOS:000337108900039
Citation statistics
Cited Times:2[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/119745
Collection中国科学院大连化学物理研究所
Corresponding AuthorTang ZC(唐紫超); Fan HJ(樊红军)
AffiliationChinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Qin, Zhengbo,Cong, Ran,Liu, Zhiling,et al. An investigation into low-lying electronic states of HCS2 via threshold photoelectron imaging[J]. JOURNAL OF CHEMICAL PHYSICS,2014,140(21):214318.
APA Qin, Zhengbo.,Cong, Ran.,Liu, Zhiling.,Xie, Hua.,Tang, Zichao.,...&樊红军.(2014).An investigation into low-lying electronic states of HCS2 via threshold photoelectron imaging.JOURNAL OF CHEMICAL PHYSICS,140(21),214318.
MLA Qin, Zhengbo,et al."An investigation into low-lying electronic states of HCS2 via threshold photoelectron imaging".JOURNAL OF CHEMICAL PHYSICS 140.21(2014):214318.
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