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学科主题物理化学
An investigation into low-lying electronic states of HCS2 via threshold photoelectron imaging
Qin, Zhengbo; Cong, Ran; Liu, Zhiling; Xie, Hua; Tang, Zichao; Fan, Hongjun; Tang ZC(唐紫超); Fan HJ(樊红军)
刊名JOURNAL OF CHEMICAL PHYSICS
2014-06-07
ISSN1089-7690
DOI10.1063/1.4879808
140期:21页:214318
收录类别SCI
合作性质
文章类型Article
部门归属11
项目归属1108,1102
产权排名待补充
WOS标题词Science & Technology ; Physical Sciences
资助者1,1 ; 1,1 ; 1,1 ; 1,1
类目[WOS]Physics, Atomic, Molecular & Chemical
研究领域[WOS]Physics
关键词[WOS]TANDEM MASS-SPECTROMETRY ; POTENTIAL-ENERGY SURFACE ; NEGATIVE-IONS ; INFRARED-SPECTRA ; CARBON-DISULFIDE ; SPECTROSCOPY ; HCO2 ; DENSITY ; ANIONS ; THIOFORMALDEHYDE
英文摘要Low-energy photoelectron imaging spectra of HCS(2)(-)are reported for the first time. Vibrationally resolved photodetachment transitions from the ground state of HCS2- to the ground state and low-lying excited states of HCS2 are observed. Combined with the ab intio calculations and Franck-Condon simulations, well-resolved vibrational spectra demonstrate definitive evidence for the resolution of the ground-state and excited states of HCS2 radical in the gaseous phase. The ground state and two low-lying excited states of HCS2 radical are assigned as B-2(2), (2)A(2), and (2)A(1) states, respectively. The adiabatic electron affinity is determined to be 2.910 +/- 0.007 eV. And the term energies of the excited states, T-0 = 0.451 +/- 0.009 eV and 0.553 +/- 0.009 eV, are directly measured from the experimental data, respectively. Angular filtering photoelectron spectra are carried out to assist in the spectral band assignment. (C) 2014 AIP Publishing LLC.
语种英语
资助者1,1 ; 1,1 ; 1,1 ; 1,1
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WOS记录号WOS:000337108900039
引用统计
被引频次:2[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/119745
专题中国科学院大连化学物理研究所
通讯作者Tang ZC(唐紫超); Fan HJ(樊红军)
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
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Qin, Zhengbo,Cong, Ran,Liu, Zhiling,et al. An investigation into low-lying electronic states of HCS2 via threshold photoelectron imaging[J]. JOURNAL OF CHEMICAL PHYSICS,2014,140(21):214318.
APA Qin, Zhengbo.,Cong, Ran.,Liu, Zhiling.,Xie, Hua.,Tang, Zichao.,...&樊红军.(2014).An investigation into low-lying electronic states of HCS2 via threshold photoelectron imaging.JOURNAL OF CHEMICAL PHYSICS,140(21),214318.
MLA Qin, Zhengbo,et al."An investigation into low-lying electronic states of HCS2 via threshold photoelectron imaging".JOURNAL OF CHEMICAL PHYSICS 140.21(2014):214318.
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