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学科主题: 物理化学
题名: Transformylating amine with DMF to formamide over CeO2 catalyst
作者: Wang, Yehong1;  Wang, Feng1;  Zhang, Chaofeng1;  Zhang, Jian1;  Li, Mingrun1;  Xu, Jie1
通讯作者: 王峰 ;  徐杰
刊名: CHEMICAL COMMUNICATIONS
发表日期: 2014
DOI: 10.1039/c3cc48400a
卷: 50, 期:19, 页:2438-2441
收录类别: SCI ;  CCR
合作性质: 
文章类型: Article
部门归属: DNL06
项目归属: DNL06T1
产权排名: 待补充
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
资助者: 1,1
研究领域[WOS]: Chemistry
英文摘要: We here report a new protocol for the formylation of various amines, primary or secondary, aromatic or alkyl, cyclic or linear, mono-or di-amine, with dimethylformamide (DMF) as the formylation reagent to obtain the corresponding formamides in good to excellent yields over CeO2 catalyst. The reaction requires no homogeneous acidic or basic additives and is tolerant to water.
关键词[WOS]: POT SELECTIVE SYNTHESIS ;  N-FORMYLATION ;  OXIDATIVE CARBONYLATION ;  IONIC LIQUIDS ;  CERIA ;  SOLVENT ;  ACID ;  CONDENSATION ;  WATER ;  CO
语种: 英语
原文出处: 查看原文
WOS记录号: WOS:000331174700010
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/119813
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China

Recommended Citation:
Wang, Yehong,Wang, Feng,Zhang, Chaofeng,et al. Transformylating amine with DMF to formamide over CeO2 catalyst[J]. CHEMICAL COMMUNICATIONS,2014,50(19):2438-2441.
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