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Controlled beta-protonation and [4+2] cycloaddition of enals and chalcones via N-heterocyclic carbene/acid catalysis: toward substrate independent reaction control
Fu, Zhenqian2; Sun, Hui1; Chen, Shaojin2; Tiwari, Bhoopendra2; Li, Guohui1; Chi, Yonggui Robin2
刊名CHEMICAL COMMUNICATIONS
2013
DOI10.1039/c2cc36564b
49期:3页:261-263
收录类别SCI ; IC
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]DIELS-ALDER REACTIONS ; ENANTIOSELECTIVE SYNTHESIS ; ALPHA,BETA-UNSATURATED ALDEHYDES ; GAMMA-BUTYROLACTONES ; EFFICIENT SYNTHESIS ; STEREOSELECTIVE-SYNTHESIS ; COOPERATIVE CATALYSIS ; NUCLEOPHILIC CARBENES ; CONJUGATE UMPOLUNG ; STETTER REACTIONS
英文摘要A substrate-independent selective generation of enolates over homoenolate equivalents in NHC-catalyzed reactions of enals and chalcones is disclosed. Acid co-catalysts play vital roles in control of the reaction pathways, allowing for individual access to diverse products from identical substrates.
语种英语
WOS记录号WOS:000311940100014
引用统计
被引频次:64[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/137481
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, State key Lab Mol React Dynam, Dalian 116023, Peoples R China
2.Nanyang Technol Univ, Sch Phys & Math Sci, Div Chem & Biol Chem, Singapore 637371, Singapore
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GB/T 7714
Fu, Zhenqian,Sun, Hui,Chen, Shaojin,et al. Controlled beta-protonation and [4+2] cycloaddition of enals and chalcones via N-heterocyclic carbene/acid catalysis: toward substrate independent reaction control[J]. CHEMICAL COMMUNICATIONS,2013,49(3):261-263.
APA Fu, Zhenqian,Sun, Hui,Chen, Shaojin,Tiwari, Bhoopendra,Li, Guohui,&Chi, Yonggui Robin.(2013).Controlled beta-protonation and [4+2] cycloaddition of enals and chalcones via N-heterocyclic carbene/acid catalysis: toward substrate independent reaction control.CHEMICAL COMMUNICATIONS,49(3),261-263.
MLA Fu, Zhenqian,et al."Controlled beta-protonation and [4+2] cycloaddition of enals and chalcones via N-heterocyclic carbene/acid catalysis: toward substrate independent reaction control".CHEMICAL COMMUNICATIONS 49.3(2013):261-263.
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