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题名: Rhodium(I)-Catalyzed Arylation of beta-Chloro Ketones and Related Derivatives through Domino Dehydrochlorination/Conjugate Addition
作者: Jiang, Quanbin1;  Guo, Tenglong1;  Wang, Qingfu1;  Wu, Ping1;  Yu, Zhengkun1, 2
关键词: arylation ;  beta-chloro ketones ;  domino reactions ;  rhodium(I) ;  sp3 CCl bond cleavage
刊名: ADVANCED SYNTHESIS & CATALYSIS
发表日期: 2013-06-01
DOI: 10.1002/adsc.201200821
卷: 355, 期:9, 页:1874-1880
收录类别: SCI ;  IC ;  CCR
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Applied ;  Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: Highly efficient arylations of -chloro ketones and their ester and amide derivatives were achieved by means of domino dehydrochlorination/Rh(I)-catalyzed conjugate addition. In situ generated vinyl ketones and their analogues were identified as the reaction intermediates. The present synthetic protocol provides a concise route to (chiral) -aryl ketones, esters, and amides.
关键词[WOS]: SECONDARY ALKYL CHLORIDES ;  SUZUKI CROSS-COUPLINGS ;  C BOND FORMATION ;  HALIDES ;  ACIDS ;  SULFONES ;  ALCOHOLS ;  BROMIDES ;  IODIDES
语种: 英语
WOS记录号: WOS:000320275600025
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/137484
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China
2.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

Recommended Citation:
Jiang, Quanbin,Guo, Tenglong,Wang, Qingfu,et al. Rhodium(I)-Catalyzed Arylation of beta-Chloro Ketones and Related Derivatives through Domino Dehydrochlorination/Conjugate Addition[J]. ADVANCED SYNTHESIS & CATALYSIS,2013,355(9):1874-1880.
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