中国科学院大连化学物理研究所机构知识库
Advanced  
DICP OpenIR  > 中国科学院大连化学物理研究所  > 期刊论文
题名: Formation of 3-pentanone via ethylene hydroformylation over Co/activated carbon catalyst
作者: Song, Xiangen1, 3;  Ding, Yunjie1, 2;  Chen, Weimiao1;  Dong, Wenda1, 3;  Pei, Yanpeng1, 3;  Zang, Juan1, 3;  Yan, Li1;  Lu, Yuan1
关键词: Ethylene hydroformylation ;  Cobalt carbonyl ;  Activated carbon ;  3-Pentanone
刊名: APPLIED CATALYSIS A-GENERAL
发表日期: 2013-02-15
DOI: 10.1016/j.apcata.2012.11.006
卷: 452, 页:155-162
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences ;  Life Sciences & Biomedicine
类目[WOS]: Chemistry, Physical ;  Environmental Sciences
研究领域[WOS]: Chemistry ;  Environmental Sciences & Ecology
英文摘要: In ethylene hydroformylation over Co/activated carbon (AC) catalyst, in addition to propanal, 3-pentanone was formed for the first time as one of a main product over heterogeneous cobalt catalyst. It was interesting to find that the properties of the supports, including both micropore proportion and the carbonaceous materials, are key factors in the formation of ketones. Based on the characterization results, cobalt carbonyl species was confirmed to be related with the formation of ketones on the surface of heterogeneous Co based catalysts. The small particle of cobalt and the high ratio of chemisorbed CO/H-2 might favor the formation of cobalt carbonyl clusters on the activated carbon supported cobalt catalysts. (c) 2012 Elsevier B.V. All rights reserved.
关键词[WOS]: RH ACTIVE-CARBON ;  COBALT CATALYSTS ;  ETHENE HYDROFORMYLATION ;  RH/ACTIVE-CARBON ;  PENTAN-3-ONE FORMATION ;  SULFIDE CATALYSTS ;  OXYGENATE FUELS ;  METAL PARTICLES ;  MONOXIDE ;  KETONES
语种: 英语
WOS记录号: WOS:000315013200020
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/137505
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

Files in This Item:

There are no files associated with this item.


作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
3.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China

Recommended Citation:
Song, Xiangen,Ding, Yunjie,Chen, Weimiao,et al. Formation of 3-pentanone via ethylene hydroformylation over Co/activated carbon catalyst[J]. APPLIED CATALYSIS A-GENERAL,2013,452:155-162.
Service
 Recommend this item
 Sava as my favorate item
 Show this item's statistics
 Export Endnote File
Google Scholar
 Similar articles in Google Scholar
 [Song, Xiangen]'s Articles
 [Ding, Yunjie]'s Articles
 [Chen, Weimiao]'s Articles
CSDL cross search
 Similar articles in CSDL Cross Search
 [Song, Xiangen]‘s Articles
 [Ding, Yunjie]‘s Articles
 [Chen, Weimiao]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
  Add to CiteULike  Add to Connotea  Add to Del.icio.us  Add to Digg  Add to Reddit 
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace