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题名: Na+/K+ switch of enantioselectivity in G-quadruplex DNA-based catalysis
作者: Wang, Changhao1;  Jia, Guoqing1;  Li, Yinghao1;  Zhang, Sufang2;  Li, Can1, 2
刊名: CHEMICAL COMMUNICATIONS
发表日期: 2013
DOI: 10.1039/c3cc45396k
卷: 49, 期:95, 页:11161-11163
收录类别: SCI ;  IC
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: Here we found that the enantioselectivity of G-quadruplex DNA-based Diels-Alder reaction can be switched by just changing Na+ to K+, which is ascribed to the structural transformation of the G-quadruplex from antiparallel to hybrid-type. By tuning the ratio of Na+/K+, the enantioselectivity of the Diels-Alder reaction could be switchable and shows much more sensitive to K+ than to Na+.
关键词[WOS]: HUMAN TELOMERE ;  K+ SOLUTION ;  ASYMMETRIC CATALYSIS ;  PEROXIDASE-ACTIVITY ;  SMALL-MOLECULE ;  ION-CHANNEL ;  DRUG DESIGN ;  NA,K-ATPASE ;  ENZYME ;  SEQUENCE
语种: 英语
WOS记录号: WOS:000326741200007
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/137530
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China

Recommended Citation:
Wang, Changhao,Jia, Guoqing,Li, Yinghao,et al. Na+/K+ switch of enantioselectivity in G-quadruplex DNA-based catalysis[J]. CHEMICAL COMMUNICATIONS,2013,49(95):11161-11163.
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