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Releasing 9.6 wt% of H-2 from Mg(NH2)(2)-3LiH-NH3BH3 through mechanochemical reaction
Cao, Hujun1,2,3; Chua, Yongshen2; Zhang, Yao4; Xiong, Zhitao2; Wu, Guotao2; Qiu, Jieshan1; Chen, Ping2
关键词Hydrogen Storage Magnesium Amide Ammonia Borane Ball Milling
刊名INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
2013-08-21
DOI10.1016/j.ijhydene.2013.06.036
38期:25页:10446-10452
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences ; Technology
类目[WOS]Chemistry, Physical ; Electrochemistry ; Energy & Fuels
研究领域[WOS]Chemistry ; Electrochemistry ; Energy & Fuels
关键词[WOS]N-H SYSTEM ; HYDROGEN STORAGE PROPERTIES ; AMMONIA-BORANE ; LITHIUM ; DESORPTION ; ABSORPTION ; SORPTION ; LIBH4 ; LIH
英文摘要Ball milling the mixture of Mg(NH2)(2), LiH and NH3BH3 in a molar ratio of 1:3:1 results in the direct liberation of 9.6 wt% H-2 (11 equiv. H), which is superior to binary systems such as LiH AB (6 equiv. H), AB-Mg(NH2)(2) (No H-2 release) and LiH-Mg(NH2)(2) (4 equiv. H), respectively. The overall dehydrogenation is a three-step process in which LiH firstly reacts with AB to yield LiNH2BH3 and LiNH2BH3 further reacts with Mg(NH2)(2) to form LiMgBN3H3. LiMgBN3H3 subsequently interacts with additional 2 equivalents of LiH to form Li3BN2 and MgNH as well as hydrogen. Copyright (C) 2013, The Authors. Published by Elsevier Ltd. All rights reserved.
语种英语
WOS记录号WOS:000324563100031
引用统计
被引频次:5[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/137543
专题中国科学院大连化学物理研究所
作者单位1.Dalian Univ Technol, Liaoning Key Lab Energy Mat & Chem Engn, State Key Lab Fine Chem, Carbon Res Lab, Dalian 116024, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
4.Southeast Univ, Sch Mat Sci & Engn, Nanjing 211189, Jiangsu, Peoples R China
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Cao, Hujun,Chua, Yongshen,Zhang, Yao,et al. Releasing 9.6 wt% of H-2 from Mg(NH2)(2)-3LiH-NH3BH3 through mechanochemical reaction[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,2013,38(25):10446-10452.
APA Cao, Hujun.,Chua, Yongshen.,Zhang, Yao.,Xiong, Zhitao.,Wu, Guotao.,...&Chen, Ping.(2013).Releasing 9.6 wt% of H-2 from Mg(NH2)(2)-3LiH-NH3BH3 through mechanochemical reaction.INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,38(25),10446-10452.
MLA Cao, Hujun,et al."Releasing 9.6 wt% of H-2 from Mg(NH2)(2)-3LiH-NH3BH3 through mechanochemical reaction".INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 38.25(2013):10446-10452.
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