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A green and efficient amine-functionalized ionic liquid/H2O catalytic system for the synthesis of alpha,alpha '-bis(substituted benzylidene)cyclopentanones
Wang, Chang1; Liu, Xiumei1; Yang, Miao1; Ma, Huiyuan1; Yan, Peifang1; Slattery, John M.2; Gao, Yanan1
刊名RSC ADVANCES
2013
DOI10.1039/c3ra40325d
3期:23页:8796-8804
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]DIRECT ALDOL REACTIONS ; SOLVENT-FREE CONDITIONS ; SUPPORTED ORGANOCATALYST ; CONDENSATION-REACTIONS ; CONVENIENT SYNTHESIS ; HIV-1 INTEGRASE ; KETONES ; ALDEHYDES ; BENZYLIDENE)CYCLOALKANONES ; PROLINE
英文摘要An environmentally benign and convenient amine-functionalized ionic liquid (IL) catalytic system was explored for the preparation of alpha,alpha'-bis(substituted benzylidene)cyclopentanones by the cross-aldol condensation of aromatic aldehydes with cyclopentanone. High yields were obtained without using any organic solvents. The condensation products can be separated easily and the ILs can be recovered and reused at least five times without apparently loss of activity. The potential mechanism of the cross-aldol condensation reaction in this IL catalytic system is discussed.
语种英语
WOS记录号WOS:000319130600027
引用统计
被引频次:6[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/137573
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian, Peoples R China
2.Univ York, Dept Chem, York YO10 5DD, N Yorkshire, England
推荐引用方式
GB/T 7714
Wang, Chang,Liu, Xiumei,Yang, Miao,et al. A green and efficient amine-functionalized ionic liquid/H2O catalytic system for the synthesis of alpha,alpha '-bis(substituted benzylidene)cyclopentanones[J]. RSC ADVANCES,2013,3(23):8796-8804.
APA Wang, Chang.,Liu, Xiumei.,Yang, Miao.,Ma, Huiyuan.,Yan, Peifang.,...&Gao, Yanan.(2013).A green and efficient amine-functionalized ionic liquid/H2O catalytic system for the synthesis of alpha,alpha '-bis(substituted benzylidene)cyclopentanones.RSC ADVANCES,3(23),8796-8804.
MLA Wang, Chang,et al."A green and efficient amine-functionalized ionic liquid/H2O catalytic system for the synthesis of alpha,alpha '-bis(substituted benzylidene)cyclopentanones".RSC ADVANCES 3.23(2013):8796-8804.
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