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Na+/K+ switch of enantioselectivity in G-quadruplex DNA-based catalysis
Wang, Changhao1; Jia, Guoqing1; Li, Yinghao1; Zhang, Sufang2; Li, Can1,2
刊名CHEMICAL COMMUNICATIONS
2013
DOI10.1039/c3cc45396k
49期:95页:11161-11163
收录类别SCI ; IC
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]HUMAN TELOMERE ; K+ SOLUTION ; ASYMMETRIC CATALYSIS ; PEROXIDASE-ACTIVITY ; SMALL-MOLECULE ; ION-CHANNEL ; DRUG DESIGN ; NA,K-ATPASE ; ENZYME ; SEQUENCE
英文摘要Here we found that the enantioselectivity of G-quadruplex DNA-based Diels-Alder reaction can be switched by just changing Na+ to K+, which is ascribed to the structural transformation of the G-quadruplex from antiparallel to hybrid-type. By tuning the ratio of Na+/K+, the enantioselectivity of the Diels-Alder reaction could be switchable and shows much more sensitive to K+ than to Na+.
语种英语
WOS记录号WOS:000326741200007
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被引频次:22[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/137579
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
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GB/T 7714
Wang, Changhao,Jia, Guoqing,Li, Yinghao,et al. Na+/K+ switch of enantioselectivity in G-quadruplex DNA-based catalysis[J]. CHEMICAL COMMUNICATIONS,2013,49(95):11161-11163.
APA Wang, Changhao,Jia, Guoqing,Li, Yinghao,Zhang, Sufang,&Li, Can.(2013).Na+/K+ switch of enantioselectivity in G-quadruplex DNA-based catalysis.CHEMICAL COMMUNICATIONS,49(95),11161-11163.
MLA Wang, Changhao,et al."Na+/K+ switch of enantioselectivity in G-quadruplex DNA-based catalysis".CHEMICAL COMMUNICATIONS 49.95(2013):11161-11163.
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