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题名: A robust Ru-PNNP catalyst system for the asymmetric hydrogenation of alpha,beta-unsaturated ketones to allylic alcohol
作者: Lu, Sheng-Mei1, 2;  Gao, Qiang1;  Li, Jun1;  Liu, Yan1;  Li, Can1
关键词: Ruthenium ;  Biphosphinobioxazoline ;  Hydrogenation ;  Unsaturated ketones ;  Allylic alcohol
刊名: TETRAHEDRON LETTERS
发表日期: 2013-12-18
DOI: 10.1016/j.tetlet.2013.10.051
卷: 54, 期:51, 页:7013-7016
收录类别: SCI ;  IC ;  CCR
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: A robust and stable Ru-Biphosphinobioxazoline catalyst system is discovered for the highly enantioselective hydrogenation of enones to allylic alcohols. A series of acyclic alpha,beta-unsaturated ketones react well affording the desired products in high yields (up to 98%) and enantioselectivities (up to 98% ee). Simple manipulation process and tolerance of water and air make this catalysis more practical and appealing. (C) 2013 Elsevier Ltd. All rights reserved.
关键词[WOS]: HIGHLY ENANTIOSELECTIVE HYDROGENATION ;  STEREOSELECTIVE HYDROGENATION ;  HETEROAROMATIC-COMPOUNDS ;  RUTHENIUM(II) COMPLEX ;  AROMATIC KETONES ;  CHIRAL LIGAND ;  HYDROSILYLATION ;  EFFICIENT ;  ALPHA
语种: 英语
WOS记录号: WOS:000327577200008
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/137645
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Cent China Normal Univ, Coll Chem, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Hubei, Peoples R China

Recommended Citation:
Lu, Sheng-Mei,Gao, Qiang,Li, Jun,et al. A robust Ru-PNNP catalyst system for the asymmetric hydrogenation of alpha,beta-unsaturated ketones to allylic alcohol[J]. TETRAHEDRON LETTERS,2013,54(51):7013-7016.
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