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题名: Conjugated microporous polymer with film and nanotube-like morphologies
作者: Tan, Dazhi1;  Xiong, Wannan1;  Sun, Hanxue3;  Zhang, Zhen1;  Ma, Wei1;  Meng, Changgong1;  Fan, Wenjie2;  Li, An3
关键词: Conjugated microporous polymers ;  Morphology ;  Two-dimension ;  Organic solvents storage
刊名: MICROPOROUS AND MESOPOROUS MATERIALS
发表日期: 2013-08-01
DOI: 10.1016/j.micromeso.2013.03.018
卷: 176, 页:25-30
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences ;  Technology
类目[WOS]: Chemistry, Applied ;  Chemistry, Physical ;  Nanoscience & Nanotechnology ;  Materials Science, Multidisciplinary
研究领域[WOS]: Chemistry ;  Science & Technology - Other Topics ;  Materials Science
英文摘要: Conjugated microporous polymer (CMP) composed of alternative phenylene and ethynylene units with film and nanotube-like morphologies were synthesized by 1,3,5-triethynylbenzene with 1,4-dibromobenzene and 1,3,5-tribromobenzene with 1,4-diethynylbenzene, respectively. Our work reveals that the morphology of CMP networks is greatly affected by the structure of monomers. We also investigated the wettability of the as-prepared CMP samples and their adsorption performance for organic solvents. The CMP samples show good surface superhydrophobicity and large BET surface area and pore volumes, making them the promising absorbent materials for separation and selective adsorption of organic contaminants or oil spills from water. (c) 2013 Elsevier Inc. All rights reserved.
关键词[WOS]: COVALENT ORGANIC FRAMEWORKS ;  TRIAZINE-BASED FRAMEWORKS ;  SURFACE-AREA ;  NETWORKS ;  PIMS
语种: 英语
WOS记录号: WOS:000320422400004
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/137654
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Dalian Univ Technol, Fac Chem Environm & Biol Sci & Technol, Expt Ctr Chem, Dalian 116024, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
3.Lanzhou Univ Technol, Coll Petrochem Technol, Lanzhou 730050, Peoples R China

Recommended Citation:
Tan, Dazhi,Xiong, Wannan,Sun, Hanxue,et al. Conjugated microporous polymer with film and nanotube-like morphologies[J]. MICROPOROUS AND MESOPOROUS MATERIALS,2013,176:25-30.
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