DICP OpenIR
Exceptional activity for direct synthesis of phenol from benzene over PMoV@MOF with O-2
Yang, Hua1,2; Li, Jun1,2; Wang, Lianyue1,2; Dai, Wen1,2,3; Lv, Ying1,2; Gao, Shuang1,2
KeywordPolyoxometalates Mofs Oxygen Benzene Phenol
Source PublicationCATALYSIS COMMUNICATIONS
2013-05-05
DOI10.1016/j.catcom.2013.02.013
Volume35Pages:101-104
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Physical
WOS Research AreaChemistry
WOS KeywordMETAL-ORGANIC FRAMEWORK ; SELECTIVE HYDROXYLATION ; MESOPOROUS SILICA ; OXIDATION ; CATALYSTS ; OXIDE ; REACTIVITY ; STABILITY ; DIOXYGEN ; HYDROGEN
AbstractThree novel catalysts named as PMo12-nVn@HKUST-1 (n=1-3) were designed and obtained through encapsulating vanadium-doped Keggin polyoxometalates (POMs) PMo12-n V-n into the framework HKUST-1 (also denoted as Cu-3(BTC)(2), MOF-199). The character structure of PMo12-n V-n@HKUST-1 was elucidated through the single crystal XRD of PMo11V@HKUST-1. Reaction rate could be greatly enhanced by PMo12-n V-n@HKUST-1 in liquid hydroxylation of benzene with O-2. Only in 20 min, a high TOF (442 h(-1)) of PMo9V3@HKUST-1 was obtained. (C) 2013 Elsevier B.V. All rights reserved.
Language英语
WOS IDWOS:000317883100020
Citation statistics
Cited Times:29[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/137675
Collection中国科学院大连化学物理研究所
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Yang, Hua,Li, Jun,Wang, Lianyue,et al. Exceptional activity for direct synthesis of phenol from benzene over PMoV@MOF with O-2[J]. CATALYSIS COMMUNICATIONS,2013,35:101-104.
APA Yang, Hua,Li, Jun,Wang, Lianyue,Dai, Wen,Lv, Ying,&Gao, Shuang.(2013).Exceptional activity for direct synthesis of phenol from benzene over PMoV@MOF with O-2.CATALYSIS COMMUNICATIONS,35,101-104.
MLA Yang, Hua,et al."Exceptional activity for direct synthesis of phenol from benzene over PMoV@MOF with O-2".CATALYSIS COMMUNICATIONS 35(2013):101-104.
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