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题名: Exceptional activity for direct synthesis of phenol from benzene over PMoV@MOF with O-2
作者: Yang, Hua1, 2;  Li, Jun1, 2;  Wang, Lianyue1, 2;  Dai, Wen1, 2, 3;  Lv, Ying1, 2;  Gao, Shuang1, 2
关键词: Polyoxometalates ;  MOFs ;  Oxygen ;  Benzene ;  Phenol
刊名: CATALYSIS COMMUNICATIONS
发表日期: 2013-05-05
DOI: 10.1016/j.catcom.2013.02.013
卷: 35, 页:101-104
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Physical
研究领域[WOS]: Chemistry
英文摘要: Three novel catalysts named as PMo12-nVn@HKUST-1 (n=1-3) were designed and obtained through encapsulating vanadium-doped Keggin polyoxometalates (POMs) PMo12-n V-n into the framework HKUST-1 (also denoted as Cu-3(BTC)(2), MOF-199). The character structure of PMo12-n V-n@HKUST-1 was elucidated through the single crystal XRD of PMo11V@HKUST-1. Reaction rate could be greatly enhanced by PMo12-n V-n@HKUST-1 in liquid hydroxylation of benzene with O-2. Only in 20 min, a high TOF (442 h(-1)) of PMo9V3@HKUST-1 was obtained. (C) 2013 Elsevier B.V. All rights reserved.
关键词[WOS]: METAL-ORGANIC FRAMEWORK ;  SELECTIVE HYDROXYLATION ;  MESOPOROUS SILICA ;  OXIDATION ;  CATALYSTS ;  OXIDE ;  REACTIVITY ;  STABILITY ;  DIOXYGEN ;  HYDROGEN
语种: 英语
WOS记录号: WOS:000317883100020
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/137675
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China

Recommended Citation:
Yang, Hua,Li, Jun,Wang, Lianyue,et al. Exceptional activity for direct synthesis of phenol from benzene over PMoV@MOF with O-2[J]. CATALYSIS COMMUNICATIONS,2013,35:101-104.
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