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题名: Conversion of furfural into cyclopentanone over Ni-Cu bimetallic catalysts
作者: Yang, Yanliang1, 2;  Du, Zhongtian1;  Huang, Yizheng1;  Lu, Fang1;  Wang, Feng1;  Gao, Jin1;  Xu, Jie1
刊名: GREEN CHEMISTRY
发表日期: 2013
DOI: 10.1039/c3gc37133f
卷: 15, 期:7, 页:1932-1940
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: The conversion of furfural into cyclopentanone over Ni-Cu bimetallic catalysts was studied under hydrogen atmosphere. Furfuryl alcohol, 4-hydroxy-2-cyclopentenone and 2-cyclopentenone were verified as three key intermediates. Rearrangement of the furan ring was independent of hydrogenation, starting from furfuryl alcohol rather than furfural. The opening and closure of the furan ring were closely related to the attack of a H2O molecule on the 5-position of furfuryl alcohol. Prior hydrogenation of the aldehyde group accounted for the different reactivity of furfural and furfuryl alcohol. The high selectivity of cyclopentanone was ascribed to the presence of 2-cyclopentenone.
关键词[WOS]: VAPOR-PHASE HYDROGENATION ;  ACIDIC IONIC LIQUIDS ;  BIOMASS ;  CHEMICALS ;  EFFICIENT ;  SUGARS ;  HYDROGENOLYSIS ;  TRANSFORMATION ;  HYDROCARBONS ;  DEHYDRATION
语种: 英语
WOS记录号: WOS:000320781200021
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/137677
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China

Recommended Citation:
Yang, Yanliang,Du, Zhongtian,Huang, Yizheng,et al. Conversion of furfural into cyclopentanone over Ni-Cu bimetallic catalysts[J]. GREEN CHEMISTRY,2013,15(7):1932-1940.
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