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题名: Synthesis of MeO-PEG-Supported Ferrocenyloxazoline Ligands and Their Application in Asymmetric Catalysis
作者: Liu Hongqiang1, 2;  Shi Lei1;  Chen Qingan1;  Wang Lei2;  Zhou Yonggui1
关键词: PEG ;  ferrocenyloxazoline ligands ;  asymmetric catalysis
刊名: ACTA CHIMICA SINICA
发表日期: 2013-01-15
DOI: 10.6023/A12110850
卷: 71, 期:1, 页:40-43
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: A simple synthesis of ferrocenyloxazoline derived chiral N,P ligands and N,S ligands immobilized on a MeO-PEG-support is described. The metal complexes of chiral ligands have been successfully applied to 1,3-dipolar cycloaddition reaction of azomethine ylides and asymmetric allylic substitution reaction, providing the products with up to 97% ee and 90% ee, respectively. The MeO-PEG-supported metal complex catalysts can be recycled easily and reused.
关键词[WOS]: 1,3-DIPOLAR CYCLOADDITION REACTIONS ;  CHIRAL FERROCENE LIGANDS ;  AZOMETHINE YLIDES ;  PLANAR CHIRALITY ;  SOLUBLE POLYMERS ;  HYDROGENATION ;  COMPLEXES ;  DERIVATIVES ;  ENANTIOSELECTIVITY ;  DIHYDROXYLATION
语种: 英语
WOS记录号: WOS:000315605300004
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/137680
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Huaibei Normal Univ, Huaibei 235000, Peoples R China

Recommended Citation:
Liu Hongqiang,Shi Lei,Chen Qingan,et al. Synthesis of MeO-PEG-Supported Ferrocenyloxazoline Ligands and Their Application in Asymmetric Catalysis[J]. ACTA CHIMICA SINICA,2013,71(1):40-43.
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