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题名: Iridium-catalyzed asymmetric hydrogenation of dibenzo[b,f][1,4]thiazepines
作者: Guo, Ran-Ning1, 2;  Gao, Kai1;  Ye, Zhi-Shi1;  Shi, Lei1;  Li, Yanqin2;  Zhou, Yong-Gui1
关键词: asymmetric hydrogenation ;  dibenzothiazepines ;  heterocyclic chemistry ;  iodine ;  iridium
刊名: PURE AND APPLIED CHEMISTRY
发表日期: 2013
DOI: 10.1351/PAC-CON-12-07-02
卷: 85, 期:4, 页:843-849
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: Highly enantioselective hydrogenation of substituted dibenzo[b,f][1,4]thiazepines was achieved with up to 96 % ee (enantiomeric excess) using [Ir(COD)Cl](2)/(R)-SynPhos complex as catalyst in the presence of iodine. This method provides an efficient access to optically active 11-substituted-10,11-dihydrodibenzo[b,f][1,4]thiazepines.
关键词[WOS]: IR-F-BINAPHANE ;  HETEROAROMATIC-COMPOUNDS ;  ENANTIOSELECTIVE HYDROGENATION ;  QUINOLINES ;  COMPLEXES ;  IMINES ;  DERIVATIVES ;  CHEMISTRY ;  LIGANDS ;  ACCESS
语种: 英语
WOS记录号: WOS:000316740300018
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/137683
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Dalian Univ Technol, Dept Chem, Dalian 116012, Peoples R China

Recommended Citation:
Guo, Ran-Ning,Gao, Kai,Ye, Zhi-Shi,et al. Iridium-catalyzed asymmetric hydrogenation of dibenzo[b,f][1,4]thiazepines[J]. PURE AND APPLIED CHEMISTRY,2013,85(4):843-849.
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