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Iridium-catalyzed asymmetric hydrogenation of dibenzo[b,f][1,4]thiazepines
Guo, Ran-Ning1,2; Gao, Kai1; Ye, Zhi-Shi1; Shi, Lei1; Li, Yanqin2; Zhou, Yong-Gui1
关键词Asymmetric Hydrogenation Dibenzothiazepines Heterocyclic Chemistry Iodine Iridium
刊名PURE AND APPLIED CHEMISTRY
2013
DOI10.1351/PAC-CON-12-07-02
85期:4页:843-849
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]IR-F-BINAPHANE ; HETEROAROMATIC-COMPOUNDS ; ENANTIOSELECTIVE HYDROGENATION ; QUINOLINES ; COMPLEXES ; IMINES ; DERIVATIVES ; CHEMISTRY ; LIGANDS ; ACCESS
英文摘要Highly enantioselective hydrogenation of substituted dibenzo[b,f][1,4]thiazepines was achieved with up to 96 % ee (enantiomeric excess) using [Ir(COD)Cl](2)/(R)-SynPhos complex as catalyst in the presence of iodine. This method provides an efficient access to optically active 11-substituted-10,11-dihydrodibenzo[b,f][1,4]thiazepines.
语种英语
WOS记录号WOS:000316740300018
引用统计
被引频次:11[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/137683
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Dalian Univ Technol, Dept Chem, Dalian 116012, Peoples R China
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GB/T 7714
Guo, Ran-Ning,Gao, Kai,Ye, Zhi-Shi,et al. Iridium-catalyzed asymmetric hydrogenation of dibenzo[b,f][1,4]thiazepines[J]. PURE AND APPLIED CHEMISTRY,2013,85(4):843-849.
APA Guo, Ran-Ning,Gao, Kai,Ye, Zhi-Shi,Shi, Lei,Li, Yanqin,&Zhou, Yong-Gui.(2013).Iridium-catalyzed asymmetric hydrogenation of dibenzo[b,f][1,4]thiazepines.PURE AND APPLIED CHEMISTRY,85(4),843-849.
MLA Guo, Ran-Ning,et al."Iridium-catalyzed asymmetric hydrogenation of dibenzo[b,f][1,4]thiazepines".PURE AND APPLIED CHEMISTRY 85.4(2013):843-849.
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