DICP OpenIR
Improved dehydrogenation/rehydrogenation performance of LiBH4 by doping mesoporous Fe2O3 or/and TiF3
Zhang, Hui1,2; Cao, Zhong1; Sun, Li-Xian2,3; Sun, Yu-Jia4; Xu, Fen5; Liu, Hui1,2; Zhang, Jian2; Huang, Zi-Qiang2; Jiang, Xia2; Li, Zhi-Bao2; Liu, Shuang2; Wang, Shuang2; Jiao, Cheng-Li2; Zhou, Huai-Ying3; Sawada, Yutaka6
KeywordLibh4 Mesoporous Iron Oxide Trifluoride Antimony Co-doped System Hydrogen Storage
Source PublicationJOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
2013-06-01
DOI10.1007/s10973-012-2721-8
Volume112Issue:3Pages:1407-1414
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Analytical ; Chemistry, Physical
WOS Research AreaChemistry
WOS KeywordHYDROGEN STORAGE PROPERTIES ; METAL-HYDRIDES ; LITHIUM BOROHYDRIDE ; CARBON ; NAALH4 ; DECOMPOSITION ; NANOPARTICLES ; DESORPTION ; AMMONIA ; SYSTEM
AbstractThe LiBH4 + mesoporous Fe2O3 (defined as M-Fe2O3) mono-doped and LiBH4 + M-Fe2O3 + TiF3 co-doped hybrid materials were prepared by ball milling process. A variety of characterization methods, such as thermogravimetric, differential scanning calorimetry, X-ray diffraction, and pressure-composition-temperature instrument, were used for examinations of the two materials' performances of storage/release of hydrogen, catalytic activity, kinetics, and thermodynamics. All the results showed that the M-Fe2O3 prepared in laboratory exhibited a good catalytic effect. Compared with the performance of M-Fe2O3 mono-doped system, M-Fe2O3 and TiF3 co-doped mode exhibits a better performance using the same additive content. Thus, the M-Fe2O3 and TiF3 co-doped mode possesses a collaborative catalytic utility with the LiBH4 hydrogen performance improved, showing a promising application.
Language英语
WOS IDWOS:000319358500031
Citation statistics
Cited Times:5[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/137691
Collection中国科学院大连化学物理研究所
Affiliation1.Changsha Univ Sci & Technol, Sch Chem & Biol Engn, Hunan Prov Key Lab Mat Protect Elect Power & Tran, Changsha 410004, Hunan, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Mat & Thermochem Lab, Dalian 116023, Peoples R China
3.Guilin Univ Elect Technol, Fac Mat Sci & Engn, Guilin 541004, Peoples R China
4.Wuhan Univ, Coll Chem & Mol Sci, Wuhan 430072, Peoples R China
5.Guilin Univ Elect Technol, Dept Mat Sci & Engn, Guilin 541004, Peoples R China
6.Tokyo Polytech Univ, Grad Sch Engn, Ctr Hyper Media Res, Atsugi, Kanagawa 2430297, Japan
Recommended Citation
GB/T 7714
Zhang, Hui,Cao, Zhong,Sun, Li-Xian,et al. Improved dehydrogenation/rehydrogenation performance of LiBH4 by doping mesoporous Fe2O3 or/and TiF3[J]. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY,2013,112(3):1407-1414.
APA Zhang, Hui.,Cao, Zhong.,Sun, Li-Xian.,Sun, Yu-Jia.,Xu, Fen.,...&Sawada, Yutaka.(2013).Improved dehydrogenation/rehydrogenation performance of LiBH4 by doping mesoporous Fe2O3 or/and TiF3.JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY,112(3),1407-1414.
MLA Zhang, Hui,et al."Improved dehydrogenation/rehydrogenation performance of LiBH4 by doping mesoporous Fe2O3 or/and TiF3".JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY 112.3(2013):1407-1414.
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