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题名: Heat capacities and thermodynamic properties of [Co(AIP)(BPY)(0.5)center dot H2O](n)center dot 2nH(2)O
作者: Li, Jiajie1, 2;  Xu, Fen2;  Si, Xiaoliang2;  Sun, Lixian2, 3;  Jiao, Qingzhu1;  Jiao, Chengli2;  Gu, Zhizhi1, 2;  Xin, He1, 2
关键词: [Co(AIP)(BPY)(0.5)center dot H2O](n)center dot 2nH(2)O ;  Coordination polymer ;  TMDSC ;  Molar heat capacity ;  TG
刊名: THERMOCHIMICA ACTA
发表日期: 2013-08-20
DOI: 10.1016/j.tca.2013.04.031
卷: 566, 页:15-18
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Analytical ;  Chemistry, Physical
研究领域[WOS]: Chemistry
英文摘要: One three-dimensional coordination polymer [Co(AIP)(BPY)(0.5)center dot H2O](n)center dot 2nH(2)O (AIP, 5-aminoisophthalic; BPY, 4,4'-bipyridine) has been synthesized solvothermally and characterized by powder X-ray diffraction, FT-IR spectra. The molar heat capacities of [Co(AIP)(BPY)(0.5)center dot H2O](n)center dot 2nH(2)O were measured by temperature modulated differential scanning calorimetry (TMDSC) over the temperature range of 188-3001K for the first time, and no phase transition or thermal anomaly was detected in the experimental temperature range. The thermodynamic parameters relative to the standard reference temperature 298.15K were derived based on the above molar heat capacities data. Besides, a two-step sequential thermal decomposition mechanism for the material was investigated through the thermogravimetry (TG-DTG) from 300 to 1073 K. (C) 2013 Elsevier B.V. All rights reserved.
关键词[WOS]: METAL-ORGANIC FRAMEWORKS ;  COORDINATION POLYMERS ;  MODULATED DSC ;  TEMPERATURE ;  STORAGE ;  WATER
语种: 英语
WOS记录号: WOS:000322685700003
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/137703
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Liaoning Normal Univ, Fac Chem & Chem Engn, Dalian 116029, Peoples R China
2.Guilin Univ Elect Technol, Sch Mat Sci & Engn, Guilin 541004, Peoples R China
3.Chinese Acad Sci, Dalian Inst Chem Phys, Mat & Thermochem Lab, Dalian 116023, Peoples R China

Recommended Citation:
Li, Jiajie,Xu, Fen,Si, Xiaoliang,et al. Heat capacities and thermodynamic properties of [Co(AIP)(BPY)(0.5)center dot H2O](n)center dot 2nH(2)O[J]. THERMOCHIMICA ACTA,2013,566:15-18.
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