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Catalytic applications of OSDA-free Beta zeolite
De Baerdemaeker, Trees1; Yilmaz, Bilge2; Mueller, Ulrich3; Feyen, Mathias3; Xiao, Feng-Shou4; Zhang, Weiping5; Tatsumi, Takashi6; Gies, Hermann7; Bao, Xinhe8; De Vos, Dirk1
KeywordBeta Zeolite Usda-free Synthesis Dealumination Alkylation Acylation Hydroconversion
Source PublicationJOURNAL OF CATALYSIS
2013-12-01
DOI10.1016/j.jcat.2013.05.025
Volume308Pages:73-81
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
WOS SubjectChemistry, Physical ; Engineering, Chemical
WOS Research AreaChemistry ; Engineering
WOS KeywordLIQUID-PHASE ALKYLATION ; LINEAR ALKYLBENZENE SYNTHESIS ; STRUCTURE-DIRECTING AGENT ; FINE CHEMICALS SYNTHESIS ; SEED-ASSISTED SYNTHESIS ; MTW-TYPE ZEOLITE ; ALUMINOSILICATE GELS ; SELECTIVE OXIDATION ; ORGANOTEMPLATE-FREE ; SOLID SOLVENTS
AbstractBeta zeolite obtained from seeded synthesis without the use of organic structure directing agents (OSDAs) has been used as a catalyst in different types of reactions. The large number of strong acid sites resulted in a high activity for the alkylation of benzene with ethene and a high cracking activity in the hydroconversion of n-decane. However, the high framework polarity resulted in fast deactivation in the acylation of aromatic ethers. Dealumination treatments resulted in improved stability in alkylation reactions with the more reactive olefins like propene. In acylation reactions, the activity was significantly increased, and in hydroconversion, a better balance between the hydrogenation/dehydrogenation and the acid sites was obtained. (C) 2013 Elsevier Inc. All rights reserved.
Language英语
WOS IDWOS:000329881700008
Citation statistics
Cited Times:36[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/137707
Collection中国科学院大连化学物理研究所
Affiliation1.Katholieke Univ Leuven, Ctr Surface Chem & Catalysis, B-3001 Heverlee, Belgium
2.BASF Corp, Chem Res & Engn, Iselin, NJ 08830 USA
3.BASF SE, Chem Res & Engn, D-67056 Ludwigshafen, Germany
4.Zhejiang Univ, Hangzhou 310028, Zhejiang, Peoples R China
5.Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116024, Peoples R China
6.Tokyo Inst Technol, Chem Resources Lab, Yokohama, Kanagawa 2268503, Japan
7.Ruhr Univ Bochum, Inst Geol Mineral & Geophys, D-44780 Bochum, Germany
8.Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
De Baerdemaeker, Trees,Yilmaz, Bilge,Mueller, Ulrich,et al. Catalytic applications of OSDA-free Beta zeolite[J]. JOURNAL OF CATALYSIS,2013,308:73-81.
APA De Baerdemaeker, Trees.,Yilmaz, Bilge.,Mueller, Ulrich.,Feyen, Mathias.,Xiao, Feng-Shou.,...&De Vos, Dirk.(2013).Catalytic applications of OSDA-free Beta zeolite.JOURNAL OF CATALYSIS,308,73-81.
MLA De Baerdemaeker, Trees,et al."Catalytic applications of OSDA-free Beta zeolite".JOURNAL OF CATALYSIS 308(2013):73-81.
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