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题名: Progress on the Catalytic Asymmetric Hydrogenation of Imines
作者: Wang Dong1;  Hou Chuanjin1, 2;  Chen Lifeng1;  Liu Xiaoning1;  An Qingda1;  Hu Xiangping2
关键词: imines ;  asymmetric catalysis ;  hydrogenation ;  chiral ligand
刊名: CHINESE JOURNAL OF ORGANIC CHEMISTRY
发表日期: 2013-07-01
DOI: 10.6023/cjoc201211036
卷: 33, 期:7, 页:1355-1368
收录类别: SCI
文章类型: Review
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: Chiral amines are important synthetic intermediates in the preparation of many physiologically active compounds. Catalytic asymmetric hydrogenation of prochiral imines represents one of the most direct and convenient route to chiral amines and their derivatives. During the past two decades, significant progress has been made in the asymmetric hydrogenation of imines. Many highly enantioselective chiral catalysts have been disclosed, some new methods and strategies have been developed, and some challenging imines substrates have been efficiently hydrogenated in high enantioselectivities. Despite these achievements, catalytic asymmetric hydrogenation of imines still have challenges of low reactivity, narrow substrate scope, harsh hydrogenation conditions and difficulty in catalyst reuse. Therefore, development of new catalyst system with high reactivity and enantioselectivity as well as environmental friendship in the asymmetric hydrogenation of imines is of great interest. This review presents a brief overview on the progress in catalytic asymmetric hydrogenation of cyclic and acyclic imines.
关键词[WOS]: N-ARYL IMINES ;  HIGHLY ENANTIOSELECTIVE HYDROGENATION ;  SUPERCRITICAL CARBON-DIOXIDE ;  PHOSPHINE-OXAZOLINE LIGANDS ;  CHIRAL TITANOCENE CATALYST ;  RU-MSDPEN CATALYSTS ;  IRIDIUM COMPLEXES ;  TRANSITION-METAL ;  CYCLIC IMINES ;  HETEROAROMATIC-COMPOUNDS
语种: 英语
WOS记录号: WOS:000323797100001
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/137778
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Dalian Polytech Univ, Sch Light Ind & Chem Engn, Dalian 116034, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

Recommended Citation:
Wang Dong,Hou Chuanjin,Chen Lifeng,et al. Progress on the Catalytic Asymmetric Hydrogenation of Imines[J]. CHINESE JOURNAL OF ORGANIC CHEMISTRY,2013,33(7):1355-1368.
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