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Chiral olefin-sulfoxide as ligands for rhodium-catalyzed asymmetric conjugate addition of arylboronic acids to unsaturated esters
Xue, Feng1,2; Wang, Dongping1; Li, Xincheng1; Wan, Boshun1
Source PublicationORGANIC & BIOMOLECULAR CHEMISTRY
2013-12-07
DOI10.1039/c3ob41342j
Volume11Issue:45Pages:7893-7898
Indexed BySCI ; IC ; CCR
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Organic
WOS Research AreaChemistry
WOS KeywordELECTRON-DEFICIENT OLEFINS ; DIENE LIGANDS ; ALPHA-DIKETONES ; BORONIC ACIDS ; ENANTIOSELECTIVE ADDITION ; 1,4-ADDITION REACTIONS ; KINETIC RESOLUTION ; ARYLATION ; KETIMINES ; 1,2-ADDITION
AbstractAn efficient rhodium/olefin-sulfoxide catalyzed asymmetric conjugate addition of organoboronic acids to various unsaturated esters has been developed, where 2-methoxy-1-naphthyl sulfinyl functionalized olefin ligands have been shown to be highly effective, and are especially applicable to unsaturated methyl esters with up to 99% yield and 91% ee.
Language英语
WOS IDWOS:000327053100011
Citation statistics
Cited Times:14[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/137780
Collection中国科学院大连化学物理研究所
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Henan Inst Sci & Technol, Coll Chem & Chem Engn, Xinxiang 453002, Henan, Peoples R China
Recommended Citation
GB/T 7714
Xue, Feng,Wang, Dongping,Li, Xincheng,et al. Chiral olefin-sulfoxide as ligands for rhodium-catalyzed asymmetric conjugate addition of arylboronic acids to unsaturated esters[J]. ORGANIC & BIOMOLECULAR CHEMISTRY,2013,11(45):7893-7898.
APA Xue, Feng,Wang, Dongping,Li, Xincheng,&Wan, Boshun.(2013).Chiral olefin-sulfoxide as ligands for rhodium-catalyzed asymmetric conjugate addition of arylboronic acids to unsaturated esters.ORGANIC & BIOMOLECULAR CHEMISTRY,11(45),7893-7898.
MLA Xue, Feng,et al."Chiral olefin-sulfoxide as ligands for rhodium-catalyzed asymmetric conjugate addition of arylboronic acids to unsaturated esters".ORGANIC & BIOMOLECULAR CHEMISTRY 11.45(2013):7893-7898.
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