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题名: Transition-metal mediated carbon-sulfur bond activation and transformations
作者: Wang, Liandi1;  He, Wei1;  Yu, Zhengkun1, 2
刊名: CHEMICAL SOCIETY REVIEWS
发表日期: 2013
DOI: 10.1039/c2cs35323g
卷: 42, 期:2, 页:599-621
收录类别: SCI
文章类型: Review
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: C-S bond activation, cleavage and transformations by means of transition metal compounds have recently become more and more important in the petroleum industry and synthetic chemistry. Homogeneous transition metal compounds have been investigated in order to provide the fundamental insight into the C-S bond cleavage in problematic organosulfur compounds such as thiophene, benzo- and dibenzothiophene derivatives. Rendering transition-metal mediated reactions with organosulfur compounds catalytic may provide promising routes to deep hydrodesulfurization of petroleum feedstocks, and offer potentially useful synthetic protocols for cross-couplings and biomimetic organic synthesis. During the last few decades increasing work was documented on C-S bond activation and transformations by means of transition metal compounds. This review summarizes the recent advances in C-S bond cleavage via the insertion of transition metals into the inert C-S bonds of these problematic organosulfur compounds, and transition-metal mediated C-S bond transformations via C-S activation through cross-couplings of thioesters, ketene dithioacetals, sulfonyl chlorides, and other diverse organosulfur compounds.
关键词[WOS]: C-S BOND ;  PALLADIUM-CATALYZED THIOCARBONYLATION ;  HIGHLY REGIOSELECTIVE THIOCARBONYLATION ;  OXO KETENE DITHIOACETALS ;  CROSS-COUPLING REACTION ;  RAY CRYSTAL-STRUCTURE ;  HDS MODEL SYSTEMS ;  SULFONYL CHLORIDES ;  EFFICIENT SYNTHESIS ;  FORMING REACTIONS
语种: 英语
WOS记录号: WOS:000312460600012
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/137790
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China
2.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

Recommended Citation:
Wang, Liandi,He, Wei,Yu, Zhengkun. Transition-metal mediated carbon-sulfur bond activation and transformations[J]. CHEMICAL SOCIETY REVIEWS,2013,42(2):599-621.
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