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Cyclization and N-Iodosuccinimide-Induced Electrophilic Iodocyclization of 3-Aza-1,5-enynes To Synthesize 1,2-Dihydropyridines and 3-Iodo-1,2-dihydropyridines
Xin, Xiaoyi; Wang, Dongping; Wu, Fan; Li, Xincheng; Wan, Boshun
刊名JOURNAL OF ORGANIC CHEMISTRY
2013-04-19
DOI10.1021/jo400387b
78期:8页:4065-4074
收录类别SCI ; IC ; CCR
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Organic
研究领域[WOS]Chemistry
关键词[WOS]STEREOSELECTIVE-SYNTHESIS ; CLAISEN REARRANGEMENT ; MOLECULAR-IODINE ; DIHYDROPYRIDINES ; DERIVATIVES ; 1,4-DIHYDROPYRIDINES ; HETEROCYCLES ; CHEMISTRY ; PYRROLES ; ACCESS
英文摘要Metal-free cyclization and N-iodosuccinimide-induced electrophilic iodocyclization of readily available 3-aza-1,5-enynes have been developed. The reactions selectively give 1,2-dihydropyridines and 3-iodo-1,2-dihydropyridines involving an aza-Claisen rearrangement and a 6p-electrocyclization step. Furthermore, the reaction could be carried out in 10 g scale for the synthesis of 1,2-dihydropyridines.
语种英语
WOS记录号WOS:000319708300009
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/137801
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
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GB/T 7714
Xin, Xiaoyi,Wang, Dongping,Wu, Fan,et al. Cyclization and N-Iodosuccinimide-Induced Electrophilic Iodocyclization of 3-Aza-1,5-enynes To Synthesize 1,2-Dihydropyridines and 3-Iodo-1,2-dihydropyridines[J]. JOURNAL OF ORGANIC CHEMISTRY,2013,78(8):4065-4074.
APA Xin, Xiaoyi,Wang, Dongping,Wu, Fan,Li, Xincheng,&Wan, Boshun.(2013).Cyclization and N-Iodosuccinimide-Induced Electrophilic Iodocyclization of 3-Aza-1,5-enynes To Synthesize 1,2-Dihydropyridines and 3-Iodo-1,2-dihydropyridines.JOURNAL OF ORGANIC CHEMISTRY,78(8),4065-4074.
MLA Xin, Xiaoyi,et al."Cyclization and N-Iodosuccinimide-Induced Electrophilic Iodocyclization of 3-Aza-1,5-enynes To Synthesize 1,2-Dihydropyridines and 3-Iodo-1,2-dihydropyridines".JOURNAL OF ORGANIC CHEMISTRY 78.8(2013):4065-4074.
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