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题名: Cyclization and N-Iodosuccinimide-Induced Electrophilic Iodocyclization of 3-Aza-1,5-enynes To Synthesize 1,2-Dihydropyridines and 3-Iodo-1,2-dihydropyridines
作者: Xin, Xiaoyi1;  Wang, Dongping1;  Wu, Fan1;  Li, Xincheng1;  Wan, Boshun1
刊名: JOURNAL OF ORGANIC CHEMISTRY
发表日期: 2013-04-19
DOI: 10.1021/jo400387b
卷: 78, 期:8, 页:4065-4074
收录类别: SCI ;  IC ;  CCR
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: Metal-free cyclization and N-iodosuccinimide-induced electrophilic iodocyclization of readily available 3-aza-1,5-enynes have been developed. The reactions selectively give 1,2-dihydropyridines and 3-iodo-1,2-dihydropyridines involving an aza-Claisen rearrangement and a 6p-electrocyclization step. Furthermore, the reaction could be carried out in 10 g scale for the synthesis of 1,2-dihydropyridines.
关键词[WOS]: STEREOSELECTIVE-SYNTHESIS ;  CLAISEN REARRANGEMENT ;  MOLECULAR-IODINE ;  DIHYDROPYRIDINES ;  DERIVATIVES ;  1,4-DIHYDROPYRIDINES ;  HETEROCYCLES ;  CHEMISTRY ;  PYRROLES ;  ACCESS
语种: 英语
WOS记录号: WOS:000319708300009
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/137801
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

Recommended Citation:
Xin, Xiaoyi,Wang, Dongping,Wu, Fan,et al. Cyclization and N-Iodosuccinimide-Induced Electrophilic Iodocyclization of 3-Aza-1,5-enynes To Synthesize 1,2-Dihydropyridines and 3-Iodo-1,2-dihydropyridines[J]. JOURNAL OF ORGANIC CHEMISTRY,2013,78(8):4065-4074.
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